604757-19-9

Upstream product

• 604757-21-3 methyl 2,3-di-O-benzyl-6-O,4-S-[(1R)-2-(phenylsulfonyl)-ethylidene]-4-thio-α-D-glucopyranoside 
• 894428-39-8 methyl 2,3-di-O-benzyl-4-S-[(Z)-2-(phenylsulfonyl)-vinyl]-4-thio-α-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 125884-36-8 methyl 6-O-benzoyl-2,3-di-O-benzyl-α-D-galactopyranoside 

Downstream Products

• 604757-21-3 methyl 2,3-di-O-benzyl-6-O,4-S-[(1R)-2-(phenylsulfonyl)-ethylidene]-4-thio-α-D-glucopyranoside 
• 894428-38-7 methyl 2,3-di-O-benzyl-4-S-[(E)-2-(phenylsulfonyl)-vinyl]-4-thio-α-D-glucopyranoside 
• 894428-39-8 methyl 2,3-di-O-benzyl-4-S-[(Z)-2-(phenylsulfonyl)-vinyl]-4-thio-α-D-glucopyranoside 

Relevant academic research and scientific papers

Vinyl bis-sulfone methodology in thiosugars: selective access to chiral thiovinyl sulfones and PSE oxathianes

Based on the vinyl bis-sulfone methodology previously developed to synthesize PSE acetals, an original approach to homochiral carbohydrate-derived PSE 1,3-oxathianes is described. The ready formation of intermediate phenylsulfonylvinyl sulfides, which hav