60504-00-9

Usage

Uses

Used in Pesticide Industry:
(3,3,3-Trichloroprop-1-enyl)benzene is used as an insecticide for controlling a broad spectrum of insects that are harmful to crops. Its application helps in protecting agricultural produce from damage caused by pests such as beetles, weevils, and moths.
Used in Fumigant Applications:
In the stored grains industry, (3,3,3-trichloroprop-1-enyl)benzene is employed as a fumigant to manage pests that can infest and damage stored grains. Its effectiveness in controlling these pests helps maintain the quality and quantity of stored food products.
Precautionary Measures:
Given its toxic nature, (3,3,3-trichloroprop-1-enyl)benzene requires careful handling to prevent skin and eye irritation, respiratory issues, and other health problems. It is crucial to adhere to safety guidelines and regulations when using this chemical to minimize its impact on human health and the environment.

InChI:InChI=1/C9H7Cl3/c10-9(11,12)7-6-8-4-2-1-3-5-8/h1-7H

Upstream product

• 993-51-1 trichloro-methanesulfonyl bromide 
• 536-74-3 phenylacetylene 
• 121-44-8 triethylamine 
• 100-42-5 styrene 
• 56-23-5 tetrachloromethane 
• 66680-87-3 (E)-1-phenyl-(2-tributylstannyl)ethene 
• 34372-27-5 (1-bromo-3,3,3-trichloropropyl)benzene 

Downstream Products

• 87406-35-7 1,1-dichloro-3-ethoxy-3-phenylpropene 
• 87406-33-5 1-phenyl-propynone-diethylacetal 
• 109497-18-9 1,1-dichloro-3,3-diphenyl-propene 
• 90348-55-3 3,3-dichloro-1-phenyl-allyl alcohol 
• 712-47-0 1.2-Dibrom-2-trifluormethyl-1-phenyl-ethylen 
• 2003-07-8 [2-bromo-3,3,3-trifluoro-1-propenyl]benzene 
• 718-65-0 3,3,3-Trifluor-1,1,2,2-tetrachlor-1-phenyl-propan 
• 2338-79-6 1-phenyl-1,2-dichloro-3,3,3-trifluoropropane 
• 772-62-3 3,3,3-trifluoro-1-phenylpropyne 
• 13991-14-5 3,4-Dichlor-1,6-diphenyl-hexa-1,3,5-trien 
• 74031-42-8 (3,3,3-trifluoroprop-1-enyl)benzene 
• 13991-16-7 3,3,4,4-Tetrachlor-1,6-diphenyl-1,5-hexadien 
• 34266-23-4 1.1-Dichlor-3-acetoxy-3-phenyl-prop-1-en 

Relevant academic research and scientific papers

Rhodium-Catalyzed Enantioselective Radical Addition of CX4 Reagents to Olefins

We describe the synthetically useful enantioselective addition of Br?CX3 (X=Cl or Br) to terminal olefins to introduce a trihalomethyl group and generate optically active secondary bromides. Computational and experimental evidence supports an asymmetric atom-transfer radical addition (ATRA) mechanism in which the stereodetermining step involves outer-sphere bromine abstraction from a [(bisphosphine)RhIIBrCl] complex by a benzylic radical intermediate. This mechanism appears unprecedented in asymmetric catalysis.

In search of the spin-delocalization effect from the correlation analysis of relative rates of the trichloromethyl-bromo-addition reactions to fourteen p-Y-substituted phenylacetylenes

A rigorous procedure was applied to the measurement of the relative rates, i.e. k(r)(Y) = k(Y)/k(H) of trichloromethyl-bromo-addition reactions to fourteen p-Y-substituted phenylacetylenes (I-Y, with Y = F, Cl, Br, Me, t-Bu, OMe, SMe, SiMe3, CF3, CN, NO2, SOMe, COMe, and CO2Me). The reaction was run in cyclohexane under nitrogen antmosphere at 65 ± 0.5°C. All products were derived from the intermediate YC6H4C = CHCCl3 adduct radicals. Correlation analysis of these rate data seems to suggest that both a polar and a spin-delocalization effect are operating at the transition state.