60509-39-9Relevant articles and documents
JOINT EFFECT OF STRUCTURAL FACTORS, TEMPERATURE, AND POLARITY OF THE MEDIUM ON RATE OF REACTIONS OF BENZYL BROMIDES WITH BUTYLAMINE. MANY-PARAMETER CORRELATIONS
Shpan'ko, I. V.,Serebryakov, I. M.,Korostylev, A. P.
, p. 1224 - 1230 (2007/10/02)
The rates of the reactions of benzyl bromides with butylamine were measured in nitrobenzene, chlorobenzene, and their mixtures at 40, 50, and 60 deg C and also in a 1:1 mixture of chlorobenzene with cyclohexane at 40 deg C.The effects of the variable factors (the structure of benzyl bromides, temperature, polarity of the medium) on the process rate were evaluated separately and in pairs and the joint effect of all three factors was also determined.The effect of the structure of the substrate and the polarity of the medium on the nature of the transition states in the reactions is discussed.