60519-99-5Relevant academic research and scientific papers
A Bifunctional MOF Catalyst Containing Metal–Phosphine and Lewis Acidic Active Sites
Prasad, Ram R. R.,Dawson, Daniel M.,Cox, Paul A.,Ashbrook, Sharon E.,Wright, Paul A.,Clarke, Matthew L.
, p. 15309 - 15318 (2018)
Post-synthetic modification of the hafnium metal–organic framework MOF-808(Hf) to include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated without oxidation to give a “MOF ligand” that can complex late transition metals such as Ir and Rh to give a bifunctional catalyst containing both metal–phosphine complexes and the Lewis acidic framework hafnium metal sites. The metallated phosphine-bearing MOFs act as fully heterogeneous bifunctional catalysts for tandem reductive amination and hydroaminomethylation reactions.
