60539-23-3

Basic information

• Product Name: ELENOLIC ACID 2-O-GLUCOSIDE
• Synonyms: ELENOLIC ACID 2-O-GLUCOSIDE;ELENOLIC ACID GLUCOSIDE(SH);Methyloleoside;Oleoside 11-methyl ester
• CAS NO: 60539-23-3
• Molecular Formula: C₁₇H₂₄O₁₁
• Molecular Weight: 404.366
• Mol File: 60539-23-3.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• Density: 1.51±0.1 g/cm3 (20 ºC 760 Torr)
• CAS DataBase Reference: ELENOLIC ACID 2-O-GLUCOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ELENOLIC ACID 2-O-GLUCOSIDE(60539-23-3)
• EPA Substance Registry System: ELENOLIC ACID 2-O-GLUCOSIDE(60539-23-3)

Safety Data

• Hazardous Substances Data: 60539-23-3(Hazardous Substances Data)

Usage

Uses

11-Methyloleoside is a secoiridoid glucoside isolated from the seeds of Fraxinus excelsior that shows differential antiinflammatory activities in LPS-treated mouse macrophage and anticancer effects in human cancer cell. 11-Methyloleoside is also a useful synthetic intermediate in the synthesis of Ligustroside (L397960).

Upstream product

• 114449-12-6 sambacolignoside 
• 30164-95-5 Oleoside dimethyl ester 
• 32619-42-4 oleuropeine 

Downstream Products

• 454212-54-5 5-ethylidene-4-[3-hydroxy-2-(2-hydroxy-1-methyl-ethyl)-5-methylcyclopentylmethoxycarbonylmethyl]-6-(3,4,5-trihydroxy-6-hydroxymethyl-tetrahydropyran-2-yloxy)-5,6-dihydro-4H-pyran-3-carboxylic acid methyl ester 
• 911218-27-4 4-{2-[2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-3-hydroxy-5-methylcyclopentylmethoxycarbonylmethyl}-5-ethylidene-6-(3,4,5-triacetoxy-6-acetoxymethyl-tetrahydropyran-2-yloxy)-5,6-dihydro-4H-pyran-3-carboxylic acid methyl ester 
• 35897-92-8 ligstroside 
• 178600-68-5 (2S,4S,E)-4-(carboxymethyl)-3-ethylidene-2-{[(2R,3S,4R,5R,6S)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl]oxy}-3,4-dihydro-2H-pyran-5-carboxylic acid 

Relevant articles and documents

Two secoiridoid glucosides from Jasminum mesnyi

Besides the known glucoside jasminin and an unidentified glucoside, two new secoiridoid glucosides,jasmoside and jasmesoside have been isolated from the leaves of Jasminum mesnyi and their structures elucidated.

Synthesis and stereochemical confirmation of the secoiridoid glucosides nudiflosides D and A

We describe herein an efficient access to the highly substituted cyclopentane unit present in the Nudifloside secoiridoid family via crotyl phosphonamide anion mediated conjugate addition to cyclopentenone.

Biosynthesis of iridoids in Syringa and Fraxinus: Secoiridoid precursors

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