60561-64-0Relevant academic research and scientific papers
Synthesis of α-amino acid amides: Ruthenium-catalyzed amination of α-hydroxy amides
Zhang, Min,Imm, Sebastian,Baehn, Sebastian,Neumann, Helfried,Beller, Matthias
supporting information; experimental part, p. 11197 - 11201 (2012/02/03)
Give me an N: The catalytic amination of α-hydroxy amides with a variety of amines, including anilines, primary and secondary aliphatic amines, and ammonia, yields a wide range of α-amino amides (see scheme). This atom-efficient amination protocol proceeds efficiently in the presence of a commercially available [Ru3(CO)12]/DCPE catalyst system. Copyright
Free-radical version of the Strecker synthesis of α-aminoamides promoted by aqueous H2O2/TiCl3/HCONH 2 system
Cannella, Rosalba,Clerici, Angelo,Panzeri, Walter,Pastori, Nadia,Punta, Carlo,Porta, Ombretta
, p. 5358 - 5359 (2007/10/03)
A new reaction of general synthetic interest representing the free-radical version of the Strecker synthesis to α-aminoamides is reported. A hydroxy radical, generated by Ti(III) one-electron reduction of H2O2, abstracts a H atom fro
