606128-63-6

Upstream product

• 606128-53-4 (1S,2S,7S)-(4-benzenesulfonyl-2,7-dimethylcyclohepta-3,5-dienyloxy)-tert-butyldimethylsilane 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 882-33-7 diphenyldisulfane 
• 606128-45-4 (1R, 2S)-2-Methyl-5-phenylsulfanylcyclohepta-3,5-dienol 
• 606128-49-8 (1S, 2S, 7S)-2,7-Dimethyl-4-phenylsulfanylcyclohepta-3,5-dienol 
• 606128-51-2 (1S, 2S, 7S)-4-Benzenesulfonyl-2,7-dimethylcyclohepta-3,5-dienol 
• 606128-32-9 (1R)-(3-benzenesulfonylcyclohepta-2,4-dienyloxy)-trimethylsilane 

Downstream Products

• 606128-93-2 (1S,5S,6R,7S)-3-benzenesulfonyl-6-(tert-butyl-dimethylsilanyloxy)-5,7-dimethylcyclohept-3-enol 

Relevant academic research and scientific papers

Functionality propagation by alkylative oxidation of cross-conjugated cycloheptadienyl sulfones

Getting the most out of sulfur. Enantiopure epoxyvinyl sulfone 1 is transformed to syn- and anti-dienyl sulfones 2 and 3, respectively, by means of a nucleophilic methylation/sulfenylation/directed elimination reaction sequence. Compound 2 has been converted into termini-differentiated seven-carbon polypropionate segments found in five biologically significant natural products.