606128-32-9

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 606128-30-7 (R)-3-Benzenesulfonyl-cyclohepta-2,4-dienol 

Downstream Products

• 606128-45-4 (1R, 2S)-2-Methyl-5-phenylsulfanylcyclohepta-3,5-dienol 
• 606128-49-8 (1S, 2S, 7S)-2,7-Dimethyl-4-phenylsulfanylcyclohepta-3,5-dienol 
• 606129-11-7 (1R,2S)-5-Benzenesulfonyl-2-methyl-cyclohepta-3,5-dienol 
• 606128-51-2 (1S, 2S, 7S)-4-Benzenesulfonyl-2,7-dimethylcyclohepta-3,5-dienol 
• 606128-55-6 (1S,2R,7S)-2-dimethylaminomethyl-7-methyl-4-phenylsulfanylcyclohepta-3,5-dienol 
• 606128-59-0 (R,2R,3R,4S,7R)-6-benzenesulfonyl-2,4-dimethyl-8-oxabicyclo[5.1.0]oct-5-en-3-ol 
• 606128-67-0 (1S, 2S, 3R, 4R, 5S)-7-Benzenesulfonyl-3,5-dimethylcyclohept-6-ene-1,2,4-triol 
• 606128-53-4 (1S,2S,7S)-(4-benzenesulfonyl-2,7-dimethylcyclohepta-3,5-dienyloxy)-tert-butyldimethylsilane 
• 606128-93-2 (1S,5S,6R,7S)-3-benzenesulfonyl-6-(tert-butyl-dimethylsilanyloxy)-5,7-dimethylcyclohept-3-enol 
• 606128-83-0 (1R,5S,6R,7S)-3-benzenesulfonyl-6-(tert-butyldimethylsilanyloxy)-5,7-dimethylcyclohept-3-enol 
• 606128-63-6 (1R,2S,3R,4S,7R)-(6-benzenesulfonyl-2,4-dimethyl-8-oxabicyclo[5.1.0]oct-5-en-3-yloxy)-tert-butyldimethylsilane 
• 606128-65-8 (1S,2S,3R,4S,7S)-(6-benzenesulfonyl-2,4-dimethyl-8-oxabicyclo[5.1.0]oct-5-en-3-yloxy)-tert-butyldimethylsilane 
• 606128-69-2 (1S,2S,5S,6R,7S)-3-benzenesulfonyl-6-(tert-butyldimethylsilanyloxy)-5,7-dimethylcyclohept-3-ene-1,2-diol 
• 606128-99-8 (1S,4S,5R,6R,7S)-2-benzenesulfonyl-5,7-bis-(tert-butyldimethylsilanyloxy)-4,6-dimethylcyclohept-2-enol 

Relevant academic research and scientific papers

Chemical synthons and intermediates

The invention provides novel six and seven-carbon termini-differentiated polypropionate stereotetrads and stereopentads useful in syntheses of natural products. The invention also provides a novel alkylative sulfenylation-desulfonylation process that efficiently transforms enantiopure epoxyvinyl sulfones to syn and anti dienylsulfides in two operations.