606128-77-2Relevant academic research and scientific papers
Functionality propagation by alkylative oxidation of cross-conjugated cycloheptadienyl sulfones
Torres, Eduardo,Chen, Yuzhong,Kim, In Chul,Fuchs
, p. 3124 - 3131 (2003)
Getting the most out of sulfur. Enantiopure epoxyvinyl sulfone 1 is transformed to syn- and anti-dienyl sulfones 2 and 3, respectively, by means of a nucleophilic methylation/sulfenylation/directed elimination reaction sequence. Compound 2 has been converted into termini-differentiated seven-carbon polypropionate segments found in five biologically significant natural products.
