6063-69-0Relevant articles and documents
Ortho-magnesiation of boron-substituted benzenes by using (TMP) 2Mg
Kawachi, Atsushi,Nagae, Saori,Onoue, Yasuhiro,Harada, Osamu,Yamamoto, Yohsuke
, p. 8005 - 8008 (2011/09/14)
Magnesiation ortho to boron: Borylbenzenes with an N-methyl-1,3- ethylenediamino group on the boron atom undergo ortho-magnesiation upon exposure to 2,2,6,6-tetramethylpiperidide (TMP)2Mg, and the resulting ortho-magnesiated borylbenzenes can be trapped with electrophiles (see scheme).