60652-08-6

Upstream product

• 63488-10-8 4-tert-butylmagnesium bromide 
• 108-94-1 cyclohexanone 
• 3972-65-4 1-bromo-4-tert-butylbenzene 

Downstream Products

• 60652-09-7 1-(p-tert-butylphenyl)cyclohexene 
• 4501-47-7 1-(tert-butyl)-4-cyclohexylbenzene 
• 1057648-16-4 6-bromo-1-(4-tert-butylphenyl)hexan-1-one 
• 42144-19-4 1-(4-(tert-butyl)phenyl)hexan-1-one 
• 1625-92-9 4-tert-butylbiphenyl 

Relevant academic research and scientific papers

Visible-Light Photoredox Catalyzed Dehydrogenative Synthesis of Allylic Carboxylates from Styrenes

The visible-light photoredox/[Co(III)] cocatalyzed dehydrogenative functionalization of cyclic and acyclic styryl derivatives with carboxylic acids is documented. The methodology enables the chemo- and regioselective allylic functionalization of styryl compounds, leading to allylic carboxylates (32 examples) under stoichiometric acceptorless conditions. Intermolecular as well as intramolecular variants are documented in high yields (up to 82%). A mechanistic rationale is also proposed on the basis of a combined experimental and spectroscopic investigation.

Electrophotochemical Ring-Opening Bromination oftert-Cycloalkanols

An electrophotochemical ring-opening bromination of unstrainedtert-cycloalkanols has been developed. This electrophotochemical method enables the oxidative transformation of cycloalkanols with 5- to 7-membered rings into synthetically useful ω-bromoketones without the use of chemical oxidants or transition-metal catalysts. Alkoxy radical species would be key intermediates in the present transformation, which generate through homolysis of the O-Br bond in hypobromite intermediates under visible light irradiation.