60652-09-7

Upstream product

• 60652-08-6 1-(4-tert-butylphenyl)cyclohexanol 
• 63488-10-8 4-tert-butylmagnesium bromide 
• 108-94-1 cyclohexanone 
• 98-54-4 para-tert-butylphenol 
• 154318-75-9 4-tert-butylphenyl triflate 
• 110-83-8 cyclohexene 
• 3972-65-4 1-bromo-4-tert-butylbenzene 

Downstream Products

• 1666-13-3 diphenyl diselenide 
• 101471-12-9 3-azido-2-(4-tert-butylphenyl)cyclohexene 
• 126421-68-9 (+/-)-trans-2-(4-tert-butylphenyl)cyclohexanol 
• 60652-12-2 (1R,2R)-1-(4-tert-Butyl-phenyl)-cyclohexane-1,2-diol 
• 101471-07-2 2-azido-1-iodo-1-(4-tert-butylphenyl)cyclohexane 
• 127047-35-2 3-thiocyanato-2-(4-t-butylphenyl)cyclohexene 

Relevant academic research and scientific papers

Visible-Light Photoredox Catalyzed Dehydrogenative Synthesis of Allylic Carboxylates from Styrenes

The visible-light photoredox/[Co(III)] cocatalyzed dehydrogenative functionalization of cyclic and acyclic styryl derivatives with carboxylic acids is documented. The methodology enables the chemo- and regioselective allylic functionalization of styryl compounds, leading to allylic carboxylates (32 examples) under stoichiometric acceptorless conditions. Intermolecular as well as intramolecular variants are documented in high yields (up to 82%). A mechanistic rationale is also proposed on the basis of a combined experimental and spectroscopic investigation.

Achieving vinylic selectivity in Mizoroki-heck reaction of cyclic olefins

In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium-hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions. Copyright

Selective arylation at the vinylic site of cyclic olefins

Cyclic olefins usually give Heck products having an aryl ring residing at the allylic or homoallylic position. We describe herein a new method that allows arylation at the vinylic position of various cyclic olefins.