606930-14-7

Upstream product

• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 97321-72-7 methyl 2,3,4-tri-O-benzyl-6-deoxy-6-phenylseleno-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 4144-87-0 methyl 6-chloro-6-deoxy-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 6304-96-7 methyl 2,3,4-tri-O-acetyl-6-deoxy-6-iodo-α-D-glucopyranoside 
• 6217-21-6 methyl 2,3,4-tri-O-acetyl-6-desoxy-α-D-xylo-hex-5-enopyranoside 
• 13265-83-3 methyl 6-deoxy-α-D-xylo-hex-5-enopyranoside 
• 100-39-0 benzyl bromide 

Downstream Products

• 110372-55-9 1D-(1,2,4/3)-2,3,4-Tri-O-benzyl-5-C-(1,3-dithian-2-yl)-1,2,3,4,5-cyclohexanpentol 
• 110453-95-7 1L-(1,3/2,4)-2,3,4-Tri-O-benzyl-5-C-(1,3-dithian-2-yl)-1,2,3,4,5-cyclohexanpentol 
• 85798-11-4 (4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one 
• 151557-63-0 ((1S,2S,3S,4R)-2,3,4-Trihydroxy-cyclohexyl)-acetic acid 
• 151557-60-7 ((1S,2S,3S,4R)-2,3,4-Trihydroxy-cyclohexyl)-acetic acid ethyl ester 
• 151557-62-9 ((1S,2S,3S,4R)-2,3,4-Tris-benzyloxy-cyclohexyl)-acetic acid ethyl ester 
• 151557-65-2 (3aS,4S,5R,6S,7R,7aS)-4,5,6-Tris-benzyloxy-7-iodo-hexahydro-benzofuran-2-one 
• 151557-54-9 N,N-Dimethyl-2-((1R,4R,5S,6S)-4,5,6-tris-benzyloxy-cyclohex-2-enyl)-acetamide 
• 151557-53-8 ((1R,4R,5S,6S)-4,5,6-Tris-benzyloxy-cyclohex-2-enyl)-acetic acid ethyl ester 
• 151557-55-0 ((1R,2S,3R,4R,5S,6S)-2,3,4-Tris-benzyloxy-5,6-dihydroxy-cyclohexyl)-acetic acid ethyl ester 
• 110372-60-6 2D-(2,4/3)-2,3,4-Tri-O-benzyl-5,5-bis-C-(ethylthio)-2,3,4-trihydroxy-1-cyclohexanon 
• 110372-61-7 2,3,4-Tri-O-benzyl-5,5-bis-C-(ethylthio)-1-O-(ethylthio)methyl-1,2,3,4-cyclohexantetrol 
• 110372-62-8 Acetic acid (2S,3R,4S)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-cyclohexyl ester 
• 107960-16-7 Acetic acid (1S,2S,3R,4S,5S)-2,3,4-tris-benzyloxy-5-cyano-5-ethylsulfanyl-cyclohexyl ester 

Relevant academic research and scientific papers

Do upper limits to the multiple spiro acetalization of the cyclohexane ring exist?

An attempt to transform the pyranoside (5) into the bifaciai ligand (3) is described. The first subtarget is acetal (13) whose conversion into tris acetal (17) is made possible by remote C-H activation. Regrettably, triol (20) does not lend itself to comparable triple cyclization.

Synthesis of cyclophellitol utilizing a palladium chloride mediated-ferrier-II rearrangement

Cyclophellitol and its C3-epimer have been synthesized from 5-enoglucopyranoside and 5-enomannopyranoside, respectively. The carbocyclic skeleton was constructed through a Ferrier-II reaction meditated by PdCl 2.

β-acarbose. I. The synthesis of 1-epivalienamine

Improvements and modifications to a literature procedure for the synthesis of multigram amounts of a derivative of 1-epivalienamine are described. As well, various other derivatives of 1-epivalienamine, of potential use in the synthesis of carba sugars, a

Mechanistic and stereochemical studies on Ferrier reaction by means of chirally deuterated glucose

The mechanism of Ferrier reaction, cyclitol formation from 5-enopyranosides, was investigated by using (E)-selectively deuterated methyl [6-2H]-2,3,4-tri-O-benzyl-α-D-xylo-hex-5-enopyranoside. The overall reaction was non-stereoselective with r

Synthesis of new aminocyclitols as potent enzymatic inhibitors

The syntheses of new pseudo-saccharides having an allylic amino moiety or an aziridine group are reported starting from methyl-α-D-glucopyranoside. To enhance the hydrophilic/lipophilic balance, pseudo-saccharides 9 and 10 were linked with a glycosyl deri