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606948-99-6

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606948-99-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 606948-99-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,0,6,9,4 and 8 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 606948-99:
(8*6)+(7*0)+(6*6)+(5*9)+(4*4)+(3*8)+(2*9)+(1*9)=196
196 % 10 = 6
So 606948-99-6 is a valid CAS Registry Number.

606948-99-6Upstream product

606948-99-6Relevant articles and documents

Large scale enantiomeric synthesis, purification, and characterization of ω-unsaturated amino acids via a Gly-Ni(II)-BPB-complex

Gu, Xuyuan,Ndungu, John M.,Qiu, Wei,Ying, Jinfa,Carducci, Michael D.,Wooden, Hank,Hruby, Victor J.

, p. 8233 - 8243 (2004)

The enantiomeric syntheses of ω-unsaturated amino acids and β-substituted ω-unsaturated amino acids were accomplished by using Gly-Ni-2[N-(N′-benzylprolyl)amino]benzophenone (BPB) as a chiral auxiliary. The synthesis provides excellent yields and high diastereoselectivities. The product crystallization followed by isomer epimerization strategy makes the reaction practical and useful for large-scale preparations. Dialkylation of the Ni(II)-complex, which was designed for mechanistic considerations, revealed that high diastereoselectivity is obtained due to the thermodynamic conformational stability of the Ni(II)-complex. The assignment of absolute configuration was accomplished by NMR, which is supported by corresponding X-ray structure and optical rotation data. Both enantiomerically pure amino acids can be synthesized in this alkylation-hydrolysis two-step strategy in multi gram scales.

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