60702-13-8

Basic information

• Product Name: p-[1-(Phenylthio)ethyl]anisole
• Synonyms: p-[1-(Phenylthio)ethyl]anisole
• CAS NO: 60702-13-8
• Molecular Formula: C₁₅H₁₆OS
• Molecular Weight: 244.35
• Mol File: 60702-13-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 362.9°C at 760 mmHg
• Flash Point: 173.3°C
• Appearance: /
• Density: 1.11g/cm³
• Vapor Pressure: 3.91E-05mmHg at 25°C
• Refractive Index: 1.597
• CAS DataBase Reference: p-[1-(Phenylthio)ethyl]anisole(CAS DataBase Reference)
• NIST Chemistry Reference: p-[1-(Phenylthio)ethyl]anisole(60702-13-8)
• EPA Substance Registry System: p-[1-(Phenylthio)ethyl]anisole(60702-13-8)

Safety Data

• Hazardous Substances Data: 60702-13-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H16OS/c1-12(17-15-6-4-3-5-7-15)13-8-10-14(16-2)11-9-13/h3-12H,1-2H3

Upstream product

• 882-33-7 diphenyldisulfane 
• 50640-96-5 (R,S)-NN-dimethyl-1-p-methoxyphenylethylamine 
• 6310-14-1 4'-methoxyacetophenone hydrazone 
• 108-98-5 thiophenol 
• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 
• 637-69-4 4-Methoxystyrene 
• 32117-52-5 1-(1-(4-methoxyphenyl)ethylidene)-2-tosylhydrazine 
• 27150-99-8 1,1-dimethoxy-1-(4-methoxyphenyl)ethane 

Downstream Products

• 107271-01-2 Methanesulfonic acid 1-benzenesulfonyl-1-(4-methoxy-phenyl)-ethyl ester 
• 107270-96-2 1-(1-Benzenesulfonyl-ethyl)-4-methoxy-benzene 

Relevant articles and documents

Transition metal-free coupling reactions of benzylic trimethylammonium salts with di(hetero)aryl disulfides and diselenides

A new protocol was developed to synthesize (enantioenriched) thioethers and selenoethers from (chiral) benzylic trimethylammonium salts and di(hetero)aryl disulfides or diselenides. These syntheses were promoted by the presence of weak base and did not require the use of any transition metal, and resulted in the target products with good to excellent yields (72-94%). Using quaternary ammonium salts synthesized from enantiomerically enriched amines led to highly enantiopure benzylic thioethers and selenoethers (94-99% ee) with configurations reversed from those of their enantioenriched quaternary ammonium salts. This journal is

Eosin-Y-Catalyzed Photoredox C?S Bond Formation: Easy Access to Thioethers

An operationally simple Eosin Y catalyzed sulfenylation of hydrazones has been realized to afford a range of thioethers under visible light. The methodology provides high yields of thioethers under ambient conditions employing readily available and inexpensive starting materials. The reaction has broad substrate scope and is compatible with various functional groups.

Selective synthesis of thioethers in the presence of a transition-metal-free solid Lewis acid

The synthesis of thioethers starting from alcohols and thiols in the presence of amorphous solid acid catalysts is reported. A silica alumina catalyst with a very low content in alumina gave excellent results in terms of both activity and selectivity also under solvent-free conditions. The reaction rate follows the electron density of the carbinol atom in the substrate alcohol and yields up to 99% and can be obtained for a wide range of substrates under mild reaction conditions.