27150-99-8

Basic information

• Product Name: 4'-Methoxyacetophenone dimethyl acetal
• Synonyms: 4'-Methoxyacetophenone dimethyl acetal
• CAS NO: 27150-99-8
• Molecular Formula: C₁₁H₁₆O₃
• Molecular Weight: 196.24
• Mol File: 27150-99-8.mol
• Article Data: 22

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4'-Methoxyacetophenone dimethyl acetal(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-Methoxyacetophenone dimethyl acetal(27150-99-8)
• EPA Substance Registry System: 4'-Methoxyacetophenone dimethyl acetal(27150-99-8)

Safety Data

• Hazardous Substances Data: 27150-99-8(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 51440-56-3 1-Methoxy-4-(1-methoxy-vinyl)-benzene 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 149-73-5 trimethyl orthoformate 
• 768-60-5 4-methoxyphenylacetylen 
• 22454-68-8 2-(1-(4-methoxyphenyl)ethylidene)-N-phenylhydrazine-1-carboxamide 
• 68969-99-3 C₁₀H₁₃O₂⁽¹⁺⁾ 
• 637-69-4 4-Methoxystyrene 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 77270-38-3 methyl 3,5-O-<(4-methoxyphenyl)ethylidene>-α-D-arabinopyranoside 
• 77397-49-0 methyl 4,6-O-<(4-methoxyphenyl)ethylidene>-α-D-glucopyranoside 
• 77525-91-8 1-methoxy-4-(1-methoxy-ethyl)-benzene 
• 67-56-1 methanol 
• 51440-56-3 1-Methoxy-4-(1-methoxy-vinyl)-benzene 
• 68969-99-3 C₁₀H₁₃O₂⁽¹⁺⁾ 

Relevant articles and documents

Bismuth subnitrate-catalyzed markovnikov-type alkyne hydrations under batch and continuous flow conditions

Bismuth subnitrate is reported herein as a simple and efficient catalyst for the atom-economical synthesis of methyl ketones via Markovnikov-type alkyne hydration. Besides an effective batch process under reasonably mild conditions, a chemically intensified continuous flow protocol was also developed in a packed-bed system. The applicability of the methodologies was demonstrated through hydration of a diverse set of terminal acetylenes. By simply switching the reaction medium from methanol to methanol-d4, valuable trideuteromethyl ketones were also prepared. Due to the ready availability and nontoxicity of the heterogeneous catalyst, which eliminated the need for any special additives and/or harmful reagents, the presented processes display significant advances in terms of practicality and sustainability.

Formation of Acetals and Ketals from Carbonyl Compounds: A New and Highly Efficient Method Inspired by Cationic Palladium

The development of a new, highly efficient, and simple method for masking carbonyl groups as acetals and ketals is described. This methodology relies on the nature of the palladium catalyst to direct the acetalization/ketalization reaction. This new protocol is mild and proceed with a very low catalyst loading at ambient temperatures. The method has been extended to a wide variety of different carbonyl compounds with various steric encumbrances to form the corresponding acetals and ketals in excellent yields.