6072-48-6Relevant academic research and scientific papers
Modulation of physical properties of ter(9,9-ditolylfluorene) by backbone-embedded heteroarenes
Wong, Ken-Tsung,Hwu, Tsyr-Yuan,Balaiah, Akula,Chao, Teng-Chih,Fang, Fu-Chuan,Lee, Ching-Tien,Peng, Ying-Chu
, p. 1415 - 1418 (2007/10/03)
Novel ter(9,9-ditolylfluorene) analogues containing thiophene and pyridine rings embedded as functional constituents within the parent hydrocarbon backbone have been synthesized. These new molecules exhibit highly efficient photoluminescence and high ther
Arylzinc species by microwave assisted Grignard formation-transmetallation sequence: Application in the Negishi coupling
Mutule, Ilga,Suna, Edgars
, p. 11168 - 11176 (2007/10/03)
Arylmagnesium species can be efficiently generated from magnesium turnings and aryl chlorides or aryl bromides under dielectric heating conditions. Subsequent microwave assisted transmetallation using ZnCl2-TMEDA afforded the corresponding arylzinc reagents. A sequential microwave assisted arylmagnesium formation-transmetallation-Negishi coupling protocol suitable for automated multiple parallel synthesis has been developed.
