60739-53-9

Basic information

• Product Name: Cyclohexanone, 4-[(tetrahydro-2H-pyran-2-yl)oxy]-
• Synonyms: Cyclohexanone,4-[(tetrahydro-2H-pyran-2-yl)oxy];4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone;4-tetrahydro-pyran-2-yloxy-cyclohexan-1-one;4-oxocyclohexanyl 2-tetrahydropyranyl ether;4-tetrahydropyran-2-yloxy-cyclohexanone;4-(2-Tetrahydropyranyloxy)-1-cyclohexanone;4-Tetrahydropyranyloxy-1-cyclohexanone;4-tetrahydropyranyloxycyclohexanone
• CAS NO: 60739-53-9
• Molecular Formula: C11H18O3
• Molecular Weight: 198.262
• Mol File: 60739-53-9.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 4-[(tetrahydro-2H-pyran-2-yl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 4-[(tetrahydro-2H-pyran-2-yl)oxy]-(60739-53-9)
• EPA Substance Registry System: Cyclohexanone, 4-[(tetrahydro-2H-pyran-2-yl)oxy]-(60739-53-9)

Safety Data

• Hazardous Substances Data: 60739-53-9(Hazardous Substances Data)

Upstream product

• 124414-02-4 2-(4,4-Dimethoxy-cyclohexyloxy)-tetrahydro-pyran 
• 556-48-9 1,4-Cyclohexanediol 
• 110-87-2 3,4-dihydro-2H-pyran 
• 13482-22-9 4-hydroxycyclohexanone 
• 64230-40-6 4-(2-Tetrahydropyranyloxy)-1-cyclohexanol 

Downstream Products

• 131057-03-9 1-methyl-4-tetrahydropyranyloxy-1-cyclohexanol 
• 147196-69-8 4-(2-Tetrahydropyranyloxy)-1-(4-(trimethylsilyl)-1,3-butadiynyl)cyclohexanol 
• 123196-48-5 (+/-)-2,2-Dimethyl-4-tetrahydropyranyloxy-1-cyclohexanone 
• 211995-75-4 4-methylene-1-(tetrahydropyran-2-yloxy)cyclohexane 
• 124414-02-4 2-(4,4-Dimethoxy-cyclohexyloxy)-tetrahydro-pyran 
• 1638679-20-5 (E)-2-cinnamyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone 
• 1345976-46-6 2-allyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone 
• 1272667-89-6 C₁₂H₁₈⁽²⁾H₂O₂ 
• 1272667-85-2 C₁₉H₂₅⁽²⁾H₂BO₄ 
• 1272667-86-3 C₁₃H₁₃⁽²⁾H₂BrO₂ 
• 1272667-88-5 C₇H₁₀⁽²⁾H₂O 
• 131077-81-1 4-[2-((3S,5S)-3,5-Dimethyl-2-oxo-5-trimethylsilanyloxy-cyclohexyl)-2-hydroxy-ethyl]-piperidine-2,6-dione 
• 131077-81-1 4-[2-((3R,5S)-3,5-Dimethyl-2-oxo-5-trimethylsilanyloxy-cyclohexyl)-2-hydroxy-ethyl]-piperidine-2,6-dione 
• 523-86-4 (+/-)-4-<2-(5-hydroxy-3,5-dimethyl-2-oxocyclohexyl)-2-hydroxyethyl>-2,6-piperidindione 

Relevant articles and documents

FeCl3·6H2O/acetaldehyde, a versatile system for the deprotection of ketals and acetals via a transacetalization process

Mild and efficient catalytic deprotection of ketals/acetals mediated by FeCl3·6H2O/acetaldehyde has been described in this paper. The versatility and high chemoselectivity of the iron(iii)/aldehyde system are demonstrated by a large scope of examples. Deprotected ketones/aldehydes are nearly quantitatively isolated after filtration over a pad of silica gel followed by evaporation of volatile by-products.

Indium(III) trifluoromethanesulfonate as an efficient catalyst for the deprotection of acetals and ketals

(Chemical Equation Presented) Acetals and ketals are readily deprotected under neutral conditions in the presence of acetone and catalytic amounts of indium(III) trifluoromethanesulfonate (0.8 mol %) at room temperature or mild microwave heating conditions to give the corresponding aldehydes and ketones in good to excellent yields.

Synthesis of 4-(1-Propynyl)-1-(5-hexene-1,3-diynyl)-1,3-cyclohexadiene and 4-(1-Propynyl)-1-(4-(trimethylsilyl)-1,3-butadiynyl)-1,3-cyclohexadiene

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