607405-74-3

Upstream product

• 607405-58-3 (1S,4S,5R)-4,7,7-trimethyl-5-[(tetrahydro-2H-pyran-2-yl)oxy]bicyclo[2.2.1]hept-2-en-2-ol trifluoromethanesulfonate 
• 607405-65-2 2-[[(1S,2R,4R)-5-allyl-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl]oxy]tetrahydro-2H-pyran 
• 923570-68-7 5-allyl-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 
• 923570-67-6 2,2-Dimethyl-propionic acid (1S,2R,4S)-5-hydrazono-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester 
• 923570-65-4 1,7,7-trimethyl-5-oxobicyclo[2.2.1]heptan-2-yl pivalate 
• 923570-66-5 5-iodo-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 
• 173044-28-5 (E)-2-bromo-4-(tert-butyldiphenylsilyloxy)-2-butene 
• 607406-40-6 (1S,4R)-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-one 
• 607405-69-6 tetrahydro-2-[[(1S,2R,4R)-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl]oxy]-2H-pyran 
• 607406-41-7 (1S,2R,4R)-2-[(E)-3-(tert-butyldiphenylsiloxy)-1-methyl-1-propenyl]-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-ol 
• 923570-69-8 5-(3-hydroxypropyl)-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 
• 607406-39-3 (1S,2R,4R)-5-[3-(methoxymethoxy)propyl]-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-ol 
• 10293-02-4 (1S,2R)-1-methyl-2-hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-5-one 
• 923570-71-2 5-(3-(methoxymethoxy)propyl)-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-yl pivalate 

Downstream Products

• 923570-76-7 (3aR,5S,6R,7S,7aR)-7-((tert-butyldiphenylsilyloxy)methyl)-2,3,3,6-tetramethyl-7a-(3-oxopropyl)-3a,4,5,6,7,7a-hexahydro-3H-inden-5-yl pivalate 
• 923570-75-6 (3aR,5S,6R,7S,7aR)-7-((tert-butyldiphenylsilyloxy)methyl)-7a-(3-hydroxypropyl)-2,3,3,6-tetramethyl-3a,4,5,6,7,7a-hexahydro-3H-inden-5-yl pivalate 
• 923570-73-4 (3aR,5S,6R,7S,7aR)-7-((tert-butyldiphenylsilyloxy)methyl)-7a-(3-(methoxymethoxy)propyl)-2,3,3,6-tetramethyl-3a,4,5,6,7,7a-hexahydro-3H-inden-5-yl pivalate 
• 923570-77-8 (3R,3aR,5aR,7S,8R,9S,9aR)-9-((tert-butyldiphenylsilyloxy)methyl)-3-hydroxy-5,5,8-trimethyl-4-methylene-decahydro-1H-cyclopenta[i]inden-7-yl pivalate 
• 923570-72-3 (3aR,5R,6R,7S,7aR)-7-((tert-butyldiphenylsilyloxy)methyl)-7a-(3-(methoxymethoxy)propyl)-2,3,3,6-tetramethyl-3a,4,5,6,7,7a-hexahydro-3H-inden-5-ol 
• 607405-77-6 (3aR,5S,6R,7S,7aR)-7-((tert-butyldiphenylsilyloxy)methyl)-7a-(3-(methoxymethoxy)propyl)-2,3,3,6-tetramethyl-3a,4,5,6,7,7a-hexahydro-3H-inden-5-ol 
• 607405-75-4 (1S,3R,4aR,7R,8S,8aR)-8-[(tert-butyldiphenylsiloxy)methyl]tetrahydro-1,3-dihydroxy-8a-[3-(methoxymethoxy)propyl]-3,4,4,7-tetramethyl-6(5H)-isochromanone 
• 607406-13-3 tert-butyl[(3'aR,6'R,7'S,7'aR)-3',3'a,4',6',7',7'a-hexahydro-7'a-[3-(methoxymethoxy)propyl]-2',3',3',6'-tetramethylspiro[1,3-dioxolane-2,5'-[5H]inden-7'-yl]methoxy]diphenylsilane 

Relevant academic research and scientific papers

Alkali metal counterion control of enolate protonation stereoselectivity

Generation of the lithium salt of the norbornenol shown (M = H) followed by quenching with aqueous NH4Cl solution gives predominantly the β-epimeric ketone 6. Similar production of the potassium alkoxide leads instead to the α-epimer (99:1). Th

Studies toward the total synthesis of dumsin. 2. A second generation approach resulting in enantioselective construction of a functionalized ABC subunit of the tetranortriterpenoid insect antifeedant

A synthesis of the ABC framework of dumsin is described. The optically active intermediate 9b, which is expeditiously assembled from 5-oxobornyl pivalate by the sequential implementation of an oxy-Cope rearrangement and an intramolecular ene reaction, pro

Total synthesis of dumsin. 1. Retrosynthetic strategy and the elaboration of key intermediates from (-)-bornyl acetate

An intramolecular anionic oxy-Cope rearrangement (44 → 46) serves as the key step in a synthetic approach to the insect antifeedant dumsin. Initial investigations clarified the manner in which (-)-bornyl acetate may be transformed into the exo-norbornenol