607405-75-4Relevant academic research and scientific papers
Total synthesis of dumsin. 1. Retrosynthetic strategy and the elaboration of key intermediates from (-)-bornyl acetate
Paquette, Leo A.,Hong, Fang-Tsao
, p. 6905 - 6918 (2007/10/03)
An intramolecular anionic oxy-Cope rearrangement (44 → 46) serves as the key step in a synthetic approach to the insect antifeedant dumsin. Initial investigations clarified the manner in which (-)-bornyl acetate may be transformed into the exo-norbornenol
