60832-18-0Relevant academic research and scientific papers
2-(3,5-Dinitrophenyl)-1,3-dithiane carbanion: A benzylic anion with a low energy triplet state
Perrotta, Raffaele R.,Winter, Arthur H.,Coldren, William H.,Falvey, Daniel E.
supporting information; scheme or table, p. 15553 - 15558 (2011/11/13)
Calculations at the DFT level predict that benzyl anions with strong π-electron-withdrawing groups in the meta position(s) have low energy diradical or triplet electronic states. Specifically, the 2-(3,5-dinitrophenyl)- 1,3-dithiane carbanion is predicted
An efficient, continuous flow technique for the chemoselective synthesis of thioacetals
Wiles, Charlotte,Watts, Paul,Haswell, Stephen J.
, p. 7362 - 7365 (2008/03/13)
By optimizing a reagent's residence time within a packed-bed reactor, it is possible to overcome selectivity issues frequently encountered in stirred reaction vessels. This important feature is demonstrated for the chemoselective protection of 4-acetylben
