60835-73-6 Usage
Uses
Used in Supramolecular Chemistry:
4'-FORMYLBENZO-15-CROWN 5-ETHER is used as a molecular recognition agent for selectively binding and transporting specific cations, particularly alkali metal ions. Its crown ether structure allows for precise ion recognition, making it a valuable tool in supramolecular chemistry.
Used in Ion-Selective Membrane Systems:
In the field of ion-selective membrane systems, 4'-FORMYLBENZO-15-CROWN 5-ETHER is used as an ionophore to facilitate the selective transport of cations across membranes. This application is crucial for the development of sensors and other devices that require precise ion control.
Used in Analytical Chemistry:
4'-FORMYLBENZO-15-CROWN 5-ETHER is used as an analytical reagent for the detection and quantification of specific cations in various samples. Its high selectivity for certain ions makes it a valuable tool in analytical chemistry for accurate and reliable measurements.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, given its potential for molecular recognition and ion sensing, 4'-FORMYLBENZO-15-CROWN 5-ETHER could be used in the pharmaceutical industry as a component in drug delivery systems or as a modifier for drug targeting and release mechanisms, enhancing the efficacy and selectivity of therapeutic agents.
Used in Environmental Applications:
Similarly, while not specified in the materials, the compound's ability to selectively bind cations could be harnessed in environmental applications for the detection and removal of specific metal ions from contaminated water sources or soil, contributing to environmental remediation efforts.
Check Digit Verification of cas no
The CAS Registry Mumber 60835-73-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,8,3 and 5 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 60835-73:
(7*6)+(6*0)+(5*8)+(4*3)+(3*5)+(2*7)+(1*3)=126
126 % 10 = 6
So 60835-73-6 is a valid CAS Registry Number.
60835-73-6Relevant academic research and scientific papers
Synthesis of formyl derivatives of benzocrown ethers containing N, S, and O heteroatoms in the macrocycle
Gromov, S. P.,Fedorova, O. A.,Vedernikov, A. I.,Samoshin, V. V.,Zefirov, N. S.,Alfimov, M. V.
, p. 116 - 123 (2007/10/02)
A method for the synthesis of 4'-bromobenzodithia-15(18)-crown-5(6) and 4'-bromobenzodiaza-15(18)-crown-5(6) by condensation of 3,4-di(2'-haloethoxy)bromobenzene with polyoxaalkanes containing terminal SH or NHMe groups was suggested.The method for the synthesis of formyl derivatives of benzocrowns containing N, S, and O heteroatoms in the macrocycle based on the metallation of appropriate bromo derivatives with BunLi followed by treatment of the resulting organolithium intermediates with DMF was developed.Oximes and semicarbazones of benzaldehydes containing a crown ether fragment were obtained, and their transformation into the original aldehydes by treatment with KNO2 in an acid medium was studied. - Key words: 4'-bromobenzocrowns, synthesis, metallation; 4'-formylbenzocrown ethers; semicarbazones and oximes of 4'-formylbenzocrown ethers.
The Photochemistry of the Host-Guest Complex. V. The Effect of the Sodium Ion on the Photoreaction of Benzil Derivatives with a Crown Ether Moiety
Hirano, Hideki,Kurumaya, Katsuyuki,Tada, Masaru
, p. 2708 - 2711 (2007/10/02)
The photolysis of 4'-(2-phenyl-1,2-dioxoethyl)benzo-15-crown-5 in benzene containing 1-dodecanethiol gives benzaldehyde and 4'-formylbenzo-15-crown-5.The formation of the aldehydes was inhibited by the sodium ion, whereas the photolysys of 1-(3,4-dimethoxyphenyl)-2-phenylethanedione was not inhibited by the sodium ion.This inhibition must be due to the decrease in the formation of benzoyl radicals from the triplet excited state of the crown ether derivative.The salt effect was discussed on the basis of the spectral data.
