60859-79-2Relevant academic research and scientific papers
Catalytic Enantioselective Synthesis of 3,4,5-Trisubstituted Isoxazoline N-Oxides and Regioselective Synthesis of 3,4,5-Trisubstituted Isoxazoles
Sahoo, Subas Chandra,Pan, Subhas Chandra
supporting information, p. 1385 - 1389 (2019/01/09)
An efficient catalytic asymmetric synthesis of 3,4,5-trisubstituted isoxazoline N-oxides and regioselective synthesis of 3,4,5-trisubstituted isoxazoles has been described. α-Nitrocinnamates and α-nitrobenzophenones were utilized as Michael acceptors resp
Asymmetric Friedel-Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst
Liu, Jingfen,Gong, Lei,Meggers, Eric
supporting information, p. 4653 - 4656 (2015/08/06)
Abstract An asymmetric Friedel-Crafts alkylation of indoles with 2-nitro-3-arylacrylates catalyzed by a metal-templated hydrogen bonding catalyst has been established. The asymmetric induction relies on chirality transfer solely from the octahedral metal
Nucleophilic addition to nitroacrylates: application towards the synthesis of 2,3-dehydroamino acids and 2,3-diamino acids
Lewandowska, Elzbieta,Wichlacz, Kinga,Sobczak, Adam J.
body text, p. 152 - 156 (2010/03/01)
The addition of the N-pronucleophiles to 2- or 3-nitro-2-alkenoates in the presence of base provided Michael addition products. In the case of 3-nitro compounds, reaction occurred via the formation of α-adducts and the subsequent elimination of nitrous ac
