60876-39-3

Upstream product

• 27316-95-6 trans-[FeCl₂(1,2-bis(dimethylphosphino)ethane)2] 
• 143-66-8 sodium tetraphenyl borate 
• 130172-25-7 {iron(II)Cl(dinitrogen)(Me₂PCH₂CH₂PMe₂)2}{BPh₄} 
• 130172-25-7 trans-bis{1,2-bis(dimethylphosphino)ethane}chloro(dinitrogen)iron(II) tetraphenylborate 

Relevant academic research and scientific papers

Isolation and Characterisation of Iron(II) Complexes with Dinitrogen, and of other Derivatives, especially from Phenylacetylene

The complex (dmpe = Me2PCH2CH2PMe2) dissolves in alcohols under dinitrogen to yield the dinitrogen complex (1+).Reactions of with PhCCH yield the interconvertible acetylide and vinylidene complexes FeCl(C

Complexes of tertiary phosphines with iron(II) and dinitrogen, dihydrogen, and other small molecules

The treatment of with sodium borohydride in ethanol produces the hydrides + in high yield.These complexes react with a variety of small molecules including N2 to give further complexes.CO2 and CS2 insert into the iron hydride bond to yield formato- and dithioformato-complexes, respectively, and carboxymethyl acetylene and phenyl acetylene yield a cyclic alkenyl complex and an acetylide, respectively.