60896-02-8

Basic information

• Product Name: Silane, trimethyl[(1Z)-1-phenyl-1-hexenyl]-
• CAS NO: 60896-02-8
• Molecular Formula: C15H24Si
• Molecular Weight: 232.441
• Mol File: 60896-02-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[(1Z)-1-phenyl-1-hexenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(1Z)-1-phenyl-1-hexenyl]-(60896-02-8)
• EPA Substance Registry System: Silane, trimethyl[(1Z)-1-phenyl-1-hexenyl]-(60896-02-8)

Safety Data

• Hazardous Substances Data: 60896-02-8(Hazardous Substances Data)

Upstream product

• 3844-94-8 1-(trimethylsilyl)-1-hexyne 
• 591-50-4 iodobenzene 
• 98-80-6 phenylboronic acid 
• 124582-31-6 (E)-1-trimethylsilyl-1-tributylstannyl-1-hexene 
• 683771-98-4 (E)-1-trimethylsilyl-1-phenyltelluro-1-hexene 
• 338999-00-1 dicyclohexyl[(Z)-1-(trimethylsilyl)hex-1-enyl]borane 
• 76346-98-0 (Z)-(1-iodo-1-hexenyl)trimethylsilane 
• 66270-63-1 [(1E)-1-iodo-hex-1-enyl]-trimethyl-silane 

Relevant articles and documents

Copper(I)-catalyzed transfer of 1-(trimethylsilyl)-1-alkenyl group from boron to tin: Regio- and stereoselective synthesis of (E)-1-(tributylstannyl)-1-(trimethylsilyl)-1-alkenes

Stereoselective transfer of 1-(trimethylsilyl)-1-alkenyl group from boron to tin has been realized by a catalytic amount of copper(I) iodide in the presence of aqueous NaOH under extremely mild reaction conditions to provide (E)-1-(tributylstannyl)-1-(trimethylsilyl)-1-alkenes (2) exclusively in good to high yields.

A facile stereoselective synthesis of (E)-α-silylvinylstannanes via hydromagnesiation of alkynylsilanes

(E)-α-Silylvinylstannanes have been synthesized by the hydromagnesiation reaction of alkynylsilanes, followed by the reaction with trialkylstannyl chlorides. (E)-α-Silylvinylstannanes can undergo the cross-coupling reaction with aryl iodides in the presence of a catalytic amounts of Pd(PPh3)4 and CuI to afford (Z)-1,2-disubstituted vinylsilanes in good yields.

Stereoselective synthesis of (E)-α-aryltellurenylvinylsilanes via hydromagnesiation reaction of alkynylsilanes

(E)-α-Aryltellurenylvinylsilanes have been synthesized stereoselectively via the hydromagnesiation of alkynylsilanes, followed by the reaction with aryltellurenyl iodides. (E)-α-Aryltellurenylvinylsilanes can undergo the cross coupling reaction with Grign