683771-98-4Relevant academic research and scientific papers
Stereoselective synthesis of (E)-α-aryltellurenylvinylsilanes via hydromagnesiation reaction of alkynylsilanes
Cai, Mingzhong,Hao, Wenyan,Zhao, Hong,Xia, Jun
, p. 1714 - 1717 (2004)
(E)-α-Aryltellurenylvinylsilanes have been synthesized stereoselectively via the hydromagnesiation of alkynylsilanes, followed by the reaction with aryltellurenyl iodides. (E)-α-Aryltellurenylvinylsilanes can undergo the cross coupling reaction with Grign
Stereoselective synthesis of (E)-α-silylvinyl tellurides via the hydrozirconation reaction of alkynylsilanes
Cai, Mingzhong,Huang, Jiadi
, p. 228 - 229 (2007/10/03)
(E)-α-silylvinyl tellurides have been synthesised stereoselectively via the hydrozirconation of alkynylsilanes, followed by reaction with aryltellurenyl iodides. (E)-α-Silylvinyl tellurides can undergo cross coupling reaction with Grignard reagents in the presence of [NiCl 2(PPh3)2] catalyst to give (Z)-1,2-disubstituted vinylsilanes in good yields.
