6092-71-3

Basic information

• Product Name: 2-methylpropyl hydroxycarbamate
• Synonyms: carbamic acid, N-hydroxy-, 2-methylpropyl ester; Isobutyl hydroxycarbamate
• CAS NO: 6092-71-3
• Molecular Formula: C₅H₁₁NO₃
• Molecular Weight: 133.1457
• Mol File: 6092-71-3.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 260°C at 760 mmHg
• Flash Point: 111°C
• Density: 1.098g/cm³
• Vapor Pressure: 0.00183mmHg at 25°C
• Refractive Index: 1.441
• CAS DataBase Reference: 2-methylpropyl hydroxycarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylpropyl hydroxycarbamate(6092-71-3)
• EPA Substance Registry System: 2-methylpropyl hydroxycarbamate(6092-71-3)

Safety Data

• Hazardous Substances Data: 6092-71-3(Hazardous Substances Data)

Upstream product

• 78-83-1 2-methyl-propan-1-ol 
• 530-62-1 1,1'-carbonyldiimidazole 
• 543-27-1 isobutyl chloroformate 

Downstream Products

• 26654-39-7 4,4-dimethyl-1,3-oxazolidin-2-one 

Relevant articles and documents

α-Nitrosostyrenes as Three-Atom Units for the (3+1) Cyclization Reaction: Facile Access to 2,3-Dihydrodiazete N-Oxides and Their Diversified Synthetic Conversions

An unprecedented (3+1) cyclization of α-nitrosostyrenes, generated in situ from α-bromooximes, and N-tosyloxycarbamates was developed, which enables the synthesis of a range of structurally unique and hitherto unexplored 2,3-dihydrodiazete N-oxides in mod

Photocatalytic Intramolecular C-H Amination Using N-Oxyureas as Nitrene Precursors

Nitrenes are remarkable high-energy chemical species that enable direct C-N bond formation, typically via controlled reactions of metal-stabilized nitrenes. Here, in contrast, the combined use of photocatalysis with careful engineering of the precursor enabled C-H amination forming imidazolidinones and related nitrogen heterocycles from readily accessible hydroxylamine precursors. Preliminary mechanistic results are consistent with the formation of free carbamoyl triplet nitrenes as reactive intermediates.

Regioselective Synthesis of 2-Vinylanilines Using O-aroyloxycarba-mates by Sequential Decarboxylation/Amination/Heck Reaction

A new sequential approach for 2-vinylanilines utilizing aryl carboxylic acids as stable, inexpensive and widely available arylating reagents is described. Employing a Pd-POVs catalyst system, this protocol is not only overcoming the restriction barrier of decarboxylative coupling to ortho-substituted substrates, but also provides site-special to create new C(sp2)-N and C(sp2)-C(sp2) bonds. Mechanistic experiments suggest the cleavage of C(sp2)-COOH gives priority to C(sp2)-X bond in this reaction.