60920-82-3

Basic information

• Product Name: BENZYL 2-ACETAMIDO-3-O-ALLYL-6-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE
• Synonyms: Benzyl 2-Acetamido-3-O-allyl-6-O-benzyl-2-deoxy-α-D-glucopyranoside;2-(AcetylaMino)-2-deoxy-6-O-(phenylMethyl)-3-O-2-propen-1-yl-α-D-glucopyranoside PhenylMethyl
• CAS NO: 60920-82-3
• Molecular Formula: C₂₅H₃₁NO₆
• Molecular Weight: 441.52
• Product Categories: Carbohydrates & Derivatives;Aromatics
• Mol File: 60920-82-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 148-149°C
• Boiling Point: 645.734°C at 760 mmHg
• Flash Point: 344.328°C
• Appearance: /
• Density: 1.201g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.575
• Storage Temp.: -20°C Freezer
• Solubility: Chloroform, Ethyl Acetate, Methanol
• PKA: 13.02±0.70(Predicted)
• Stability: Store in Freezer
• CAS DataBase Reference: BENZYL 2-ACETAMIDO-3-O-ALLYL-6-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL 2-ACETAMIDO-3-O-ALLYL-6-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE(60920-82-3)
• EPA Substance Registry System: BENZYL 2-ACETAMIDO-3-O-ALLYL-6-O-BENZYL-2-DEOXY-ALPHA-D-GLUCOPYRANOSIDE(60920-82-3)

Safety Data

• Hazardous Substances Data: 60920-82-3(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

InChI:InChI=1/C25H31NO6/c1-3-14-30-24-22(26-18(2)27)25(31-16-20-12-8-5-9-13-20)32-21(23(24)28)17-29-15-19-10-6-4-7-11-19/h3-13,21-25,28H,1,14-17H2,2H3,(H,26,27)/t21?,22-,23+,24+,25-/m0/s1

Upstream product

• 60920-73-2 benzyl 2-acetamido-3-O-allyl-2-deoxy-α-D-glucopyranoside 
• 13343-63-0 benzyl 4,6-O-benzylidene-2-acetylamino-2-deoxy-α-D-glucopyranoside 
• 10036-64-3 N-acetyl-D-glucosamine 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 106-95-6 allyl bromide 
• 100-51-6 benzyl alcohol 
• 74352-45-7 benzyl 2-acetamido-3-O-allyl-2-deoxy-6-O-tosyl-α-D-glucopyranoside 
• 20194-18-7 sodium phenyl-methanolate 
• 60920-72-1 benzyl 2-acetamido-3-O-allyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 

Downstream Products

• 136514-60-8 Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-((2R,3S,4R,5R,6S)-5-acetylamino-4-allyloxy-6-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester 
• 152932-79-1 Chloro-acetic acid (2R,3S,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-((2R,3S,4R,5R,6S)-5-acetylamino-4-allyloxy-6-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester 
• 210645-13-9 benzyl 3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-allyl-6-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 1227930-23-5 benzyl 2-acetamido-3-O-allyl-6-O-benzyl-2-deoxy-4-O-methanesulfonyl-α-D-glucopyranoside 
• 77345-44-9 benzyl 2-acetamido-3-O-allyl-6-O-benzyl-2-deoxy-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 136514-62-0 C₆₈H₇₇NO₁₈ 
• 136543-98-1 N-[(2S,3R,4R,5S,6R)-2-Benzyloxy-6-benzyloxymethyl-5-((2S,3R,4S,5R,6R)-6-benzyloxymethyl-3,4,5-trihydroxy-tetrahydro-pyran-2-yloxy)-4-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-acetamide 
• 136514-61-9 Acetic acid (2S,3R,4S,5S,6R)-4,5-diacetoxy-2-((2R,3S,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yloxy)-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester 
• 112302-97-3 N-<2-O--glycoloyl>-L-α-aminobutanoyl-D-isoglutamine benzyl ester 
• 112302-98-4 N-[(2S,3R,4R,5S,6R)-2-((2R,3S,4R,5R,6S)-5-Acetylamino-4-allyloxy-6-benzyloxy-2-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl]-N-benzyl-acetamide 
• 112302-95-1 benzyl 2-acetamido-4-O-(2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-6-O-benzyl-2-deoxy-3-O-<(methoxycarbonyl)methyl>-α-D-glucopyranoside 
• 112302-96-2 benzyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl-(1→4)-2-acetamido-6-O-benzyl-3-O-carboxymethyl-2-deoxy-α-D-glucopyranoside 
• 73440-93-4 benzyl 2-acetamido-4-O-(2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-6-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 112302-99-5 benzyl 2-acetamido-4-O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-3-O-allyl-6-O-benzyl-2-deoxy-α-D-glucopyranoside 

Relevant articles and documents

Carbohydrates as Nucleophiles in Conjugate Addition for Preparation of Muramic Acid Analogues

Benzyl 2-acetamido-6-O-benzyl-3-O--α-D-glucopyranoside (15) was synthesized stereoselectively by conjugate addition reaction, starting from benzyl 2-acetamido-6-O-benzyl-2-deoxy-α-D-glucopyranoside (9) and crotonic acid ethyl este

THE SYNTHESIS OF O-(2-ACETAMIDO-2-DEOXY-β-D-GLUCOPYRANOSYL)-(1->4)-N-ACETYLNORMURAMOYL-L-α-AMINOBUTANOYL-D-ISOGLUTAMINE

Benzyl 2-acetamido-3-O-allyl-6-O-benzyl-2-deoxy-4-O-(3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-α-D-glucopyranoside (4) was obtained in high yield on using the silver triflate method in the absence of base.Compound 4 was converted in six