609344-52-7Relevant academic research and scientific papers
Isolation of a 1,2-dialuminacyclobutene
Cui, Chunming,Li, Xiaofei,Wang, Chunhua,Zhang, Jianying,Cheng, Jinpei,Zhu, Xiaoqing
, p. 2245 - 2247 (2007/10/03)
Aluminum siding: Reduction of Ar′All2 (Ar′ = 2,6-Dipp2C6H3, Dipp = 2,6-iPr2C 6H3) in the presence of Me3SiCCSiMe3 afforded (Ar′Al)2(CSiMe3)2 (see picture), a dialuminum-substituted cyclobutene analogue. The central four-membered Al2C2 ring adopts a folded geometry and is isoelectronic with aromatic cyclobutadiene dications. (Figure Presented)
The [2 + 4] Diels-Alder cycloadditon product of a probable dialuminene, Ar′AlAlAr′ (Ar′ = C6H3- 2,6-Dipp 2; Dipp = C6H3-2,6-Pri2), with toluene
Wright, Robert J.,Phillips, Andrew D.,Power, Philip P.
, p. 10784 - 10785 (2007/10/03)
Reduction of Ar′AlI2 (Ar′ = Ar′= C6H3-2,6-Dipp2; Dipp = C6H3-2,6-Pri2) with KC8 in diethyl ether most probably affords the first dialuminene , Ar′AlAlAr′; it was characterized by its reaction with toluene which yielded a [2 + 4] cycloaddition product incorporating the Ar′AlAlAr′ unit. Copyright
