60972-00-1

Basic information

• Product Name: 2,5-dihydro-4-methyl-5-<(1-methyl-2-oxocyclohexyl)methyl>-2-oxo-3-furancarboxylic acid methyl ester
• Synonyms: 2,5-dihydro-4-methyl-5-<(1-methyl-2-oxocyclohexyl)methyl>-2-oxo-3-furancarboxylic acid methyl ester
• CAS NO: 60972-00-1
• Molecular Weight: 280.321
• Mol File: 60972-00-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-dihydro-4-methyl-5-<(1-methyl-2-oxocyclohexyl)methyl>-2-oxo-3-furancarboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-dihydro-4-methyl-5-<(1-methyl-2-oxocyclohexyl)methyl>-2-oxo-3-furancarboxylic acid methyl ester(60972-00-1)
• EPA Substance Registry System: 2,5-dihydro-4-methyl-5-<(1-methyl-2-oxocyclohexyl)methyl>-2-oxo-3-furancarboxylic acid methyl ester(60972-00-1)

Safety Data

• Hazardous Substances Data: 60972-00-1(Hazardous Substances Data)

Upstream product

• 74063-80-2 2,5-dihydro-4,5-dimethyl-5-methoxy-2-oxo-3-furancarboxylic acid methyl ester 
• 60971-97-3 2,5-dihydro-5-hydroxy-4,5-dimethyl-2-oxo-3-furancarboxylic acid 
• 60971-98-4 2,5-dihydro-5-hydroxy-4,5-dimethyl-2-oxo-3-furancarboxylic acid methyl ester 
• 60971-99-5 2,5-dihydro-4-methyl-5-methylene-2-oxo-3-furancarboxylic acid methyl ester 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 

Downstream Products

• 74064-03-2 3aβ,4,4aα,5,6,7,8,8a,9,9aβ-decahydro-3β,8aβ-dimethyl-5-methylene-3β-(phenylthio)naphtho<2,3-b>furan-2(3H)-one 
• 74064-03-2 3aβ,4,4aα,5,6,7,8,8a,9,9aβ-decahydro-3α,8aβ-dimethyl-5-methylene-3β-(phenylthio)naphtho<2,3-b>furan-2(3H)-one 
• 470-17-7 dl-7,8-epiisoalantolactone 
• 74064-09-8 2,3,3aβ,5,6,7,8,8a,9,9aβ-decahydro-8aβ-methyl-2-oxo-5β-(phenylthio)naphtho<2,3-b>furan-3-carboxylic acid methyl ester 
• 74064-07-6 2,3,3aβ,4,6,7,8,8a,9,9aβ-decahydro-8aβ-methyl-2-oxo-4β-(phenylthio)naphtho<2,3-b>furan-3-carboxylic acid methyl ester 
• 546-43-0 dl-7,8-epialantolactone 
• 1856-58-2 (+/-)-dihydrocallitrisin 

Relevant articles and documents

An Annelation Approach to the Synthesis of Eudesmane and Elemane Sesquiterpene Lactones. Total Synthesis of dl-Dihydrocallitrisin, dl-7,8-Epialantolactone, dl-7,8-Epiisoalantolactone, and dl-Atractylon

An annelation approach to the synthesis of eudesmane sesquiterpenes is described.The 1,6-annelation reagent α-carbomethoxy-β-methyl-γ-methylidene-Δα,β-butenolide (1) is used to construct the linear tricyclic lactone 2,5,6,7,8,8a,9,9aβ-octahydro-8aβ-methyl-2-oxonaphthofuran-3-carboxylic acid methyl ester (2).The conversion of 2 to dl-dihydrocallitrisin (3), dl-7,8-epialantolactone (4), dl-7,8-epiisoalantolactone (5), and dl-atractylon (6) is detailed.Studies directed toward synthesis of the elemane sesquiterpene lactones vernomenin and vernolepin also are presented.