609810-35-7Relevant academic research and scientific papers
C-H bond activation by [{(Diimine)Pd(μ-OH)}2]2+ dimers: Mechanism-guided catalytic improvement
Bercaw, John E.,Hazari, Nilay,Labinger, Jay A.,Oblad, Paul F.
, p. 9941 - 9943 (2008)
(Chemical Equation Presented) Clearly different: The mechanism of C-H activation by air- and water-tolerant complexes of the type [{(diimine)Pd(μ- OH)}2]2+ (see scheme; Ar=tBu2C 6H3, solv=MeOH or trifluoroethanol) and [(diimine)Pd(OH2)2]2+ has been investigated. Surprisingly, there are significant mechanistic differences in activation by the dimeric Pd complex and the analogous Pt species, with the Pd species found to be considerably more reactive.
