610300-85-1

Upstream product

• 38651-65-9 (1R,5S)-(+)-nopinone 

Downstream Products

• 610300-90-8 2-[(1S,2R,3S,5R)-3-(diphenylphosphoryl)-6,6-dimethylbicyclo[3.1.1]hept-2-yl]-6-phenylpyridine 
• 610300-78-2 2-[(1S,2R,3S,5R)-3-(diphenylphosphino)-6,6-dimethylbicyclo[3.1.1]hept-2-yl]-6-phenylpyridine 
• 610300-86-2 2-phenyl-6-[(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]pyridine 

Relevant academic research and scientific papers

t-BuOK-mediated hydrophosphination of functionalized alkenes: A novel synthesis of chiral P,N- and P,P-ligands

A novel synthesis of effective chiral P,N- and P,P-ligands has been developed by using a t-BuOK-mediated hydrophosphination of chiral alkenylpyridines and alkenylphosphine oxides. Ir complexes of chiral P,N-ligands 1 and 3 gave high enantioselectivities for the hydrogenation of (Z)-α-(acetamido)cinnamate 25 and (E)-1,2-diphenylpropene leading to the hydrogenated products with up to 97% ee.