61057-38-3Relevant academic research and scientific papers
Solventless Reactions for the Synthesis of Organotin Clusters and Cages
Chandrasekhar, Vadapalli,Baskar, Viswanathan,Boomishankar, Ramamoorthy,Gopal, Kandasamy,Zacchini, Stefano,Bickley, Jamie F.,Steiner, Alexander
, p. 3710 - 3716 (2003)
Organotin clusters and cages have been synthesized in quantitative yields by using a benign solventless synthetic methodology. Using this method a variety of structural forms, which include the drum, O-capped cluster, tetranuclear oxo cage, discrete, and polymeric compounds, have been synthesized. All these compounds (1-11) have been characterized by spectroscopic and analytical techniques. The new compounds, which include the hexameric drum [n-BuSn(O)OCOAd]6 (Ad = adamantyl) 9, a triorganotin-based discrete structure Ph3SnO2C-C6-H 22,4,6-Me3 (10), and a polymer Ph3SnOSO 2-C6H3-2,5-Me2 (11), have been characterized by single-crystal X-ray crystallography.
First example of a Sn-C bond cleaved product in the reaction of Ph3SnOSnPh3 with carboxylic acids. 3D-Supramolecular network formation in the X-ray crystal structure of [Ph2Sn(OH)OC(O)(Rf)]2, Rf = 2,4,6-(CF3)3C6H2
Chandrasekhar, Vadapalli,Nagendran, Selvarajan,Gopal, Kandasamy,Steiner, Alexander,Zacchini, Stefano
, p. 862 - 863 (2003)
A 1:2 reaction of Ph3SnOSnPh3 1 with RfCOOH 2 leads to the formation of [Ph2Sn(OH)OC(O)(Rf)]2 3, by means of a facile Sn-C bond cleavage process.
