61064-95-7Relevant academic research and scientific papers
1,2-Ferrocenediylazaphosphinines 2: A new class of nucleophilic catalysts for ring-opening of epoxides
Paek, Seung Hwan,Shim, Sang Chul,Cho, Chan Sik,Kim, Tae-Jeong
, p. 849 - 851 (2003)
1,2-Ferrocenediylazaphosphinines (1a-c) have been successfully employed as a new class of nucleophilic catalysts for ring-opening of a range of epoxides, their catalytic efficiency in terms of regioselectivity as well as chemical yield comparing well with the existing catalysts in the literature. In contrast, low enantiomeric excesses have been obtained from the reactions of meso-epoxides catalyzed by (R)-1.
SODIUM BROMIDE CATALYSED REGIOSELECTIVE CLEAVAGE OF OXIRANES WITH CHLOROTRIMETHYLSILANE
Iqbal, Javed,Khan, M. Amin,Ahmad, Saeed
, p. 641 - 644 (2007/10/02)
Sodium bromide efficiently catalyses the regioselective cleavage of oxiranes with chlorotrimethylsilane to the corresponding O-silyiated chlorohydrins in excellent yield.
ACTION D'HALOGENOSILANES SUR LES OXYDES DE VINYL-2 FURANNE, DE STYRENE ET DE BUTENE-1. ETUDE DES REGIO ISOMERES PAR RMN-(13)C
Maraval, M.,Borredon, M. E.,Delmas, M.,Dubac, J.,Gaset, A.
, p. 3307 - 3310 (2007/10/02)
(13)C-NMR shows that the regiochemistry of the reaction of a halosilane Me3SiX (X=Cl, Br) on a dissymetric epoxide depends of R: RCHXCH2OSiMe3 (a, R=2-Fu, Ph) or RCHOSiMe3CH2X (b, R=Et, b>a).
