61074-17-7Relevant articles and documents
Regioselective De-O-benzylation with Lewis Acids
Hori, Hiroshi,Nishida, Yoshihiro,Ohrui, Hiroshi,Meguro, Hiroshi
, p. 1346 - 1353 (2007/10/02)
Simple and highly regioselective de-O-benzylations of poly-O-benzylated monosaccharides and polyols with Lewis acids (SnCl4 and TiCl4) were developed.Spectral studies on intermediates complexes showed that three appropriately situated metal chelating functional groups were necessary for the selective de-O-benzylation.
Synthesis of the colitose determinant of Escherichia coli O111 and 3,6-di-O-(α-D-galactopyranosyl)-α-D-glucopyranoside
Iversen, Tommy,Bundle, David R.
, p. 299 - 303 (2007/10/02)
The synthesis of two branched trisaccharides, which constitute important elements of enterobacterial lipopolysaccharides are described.The common structural feature of each trisaccharide is α-D-glucopyranoside, upon which branching occurs at the O-3 and O