61134-30-3

Basic information

• Product Name: benzyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside
• Synonyms: benzyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside
• CAS NO: 61134-30-3
• Molecular Weight: 540.656
• Mol File: 61134-30-3.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: benzyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside(61134-30-3)
• EPA Substance Registry System: benzyl 3,4,6-tri-O-benzyl-α-D-mannopyranoside(61134-30-3)

Safety Data

• Hazardous Substances Data: 61134-30-3(Hazardous Substances Data)

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 100-51-6 benzyl alcohol 
• 100-39-0 benzyl bromide 
• 82703-48-8 3,4,6-tri-O-benzyl-1,2-O-(1-benzyloxyethylidene)-β-D-mannopyranose 
• 61134-29-0 benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 3947-62-4 2,3,4,5-tetra-O-acetyl-D-glucopyranose 
• 108869-64-3 3,4,6-tri-O-benzyl-2-O-acetyl-α-D-glucosyl trichloroimidate 
• 51532-75-3 3,4,6-tri-O-benzyl-1,2-O-(1-methoxyethylidene)-α-D-glucopyranose 
• 3254-16-8 3,4,6-tri-O-acetyl-[1,2-O-(1-methoxyethylidene)]-α-D-glucopyranose 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 1380516-32-4 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate 
• 604-69-3 β-D-glucose pentaacetate 
• 82703-48-8 3,4,6-tri-O-benzyl-1,2-O-(1-benzyloxyethylidene)-α-D-glucopyranose 
• 4258-14-4 3,4,6-tri-O-acetyl-1,2-O-(1-benzyloxyethylidene)-α-D-glucopyranose 

Downstream Products

• 185380-50-1 (2S,3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-((2R,3R,4S,5R,6R)-2,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-2-carboxylic acid benzyl ester 
• 705951-26-4 ((2S,3S,4S,5R,6R)-2,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yloxy)-acetic acid tert-butyl ester 
• 82703-49-9 benzyl 2-O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 1423019-37-7 benzyl 3,4,6-tri-O-benzyl-β-d-arabino-hexos-2-ulo-pyranoside 
• 61134-29-0 benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranoside 
• 144261-01-8 benzyl 2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 112289-03-9 benzyl O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-acetyl-α-D-glucopyranosyl)-(1->2)-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 105285-88-9 benzyl 3,4,6-tri-O-benzyl-2-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-α-D-mannopyranoside 
• 137063-46-8 C₆₁H₆₄O₁₀ 
• 137063-45-7 C₆₁H₆₄O₁₀ 

Relevant articles and documents

Exploring the Biochemical Foundations of a Successful GLUT1-Targeting Strategy to BNCT: Chemical Synthesis and in Vitro Evaluation of the Entire Positional Isomer Library of ortho-Carboranylmethyl-Bearing Glucoconjugates

Boron neutron capture therapy (BNCT) is a noninvasive binary therapeutic modality applicable to the treatment of cancers. While BNCT offers a tumor-targeting selectivity that is difficult to match by other means, the last obstacles preventing the full har

An Unexpected FeCl 3/C-Catalyzed β-Stereoselective Glycosylation in the Presence of the C(2)-Benzyl Group

An efficient and completely β-stereoselective glycosylation that did not rely on neighboring group participation is described using 2-20 molpercent FeCl 3 /C as the catalyst and benzylated propargyl glycosides as the donors to reach yields up to 96percent under mild condition. With an octatomic-ring intermediate at the α-face of FeCl 3 /C with alkyne of propargyl glycosides, a panel of aglycones comprising aliphatic, alicyclic, unsaturated alcohols, halogenated alcohols, and phenols with different substitution were examined successfully for the exclusive β-stereoselective glycosylation reaction.

Glycosyl dithiocarbamates: β-selective couplings without auxiliary groups

In this article, we evaluate glycosyl dithiocarbamates (DTCs) with unprotected C2 hydroxyls as donors in β-linked oligosaccharide synthesis. We report a mild, one-pot conversion of glycals into β-glycosyl DTCs via DMDO oxidation with subsequent ring opening by DTC salts, which can be generated in situ from secondary amines and CS2. Glycosyl DTCs are readily activated with Cu(I) or Cu(II) triflate at low temperatures and are amenable to reiterative synthesis strategies, as demonstrated by the efficient construction of a tri-β-1,6-linked tetrasaccharide. Glycosyl DTC couplings are highly β-selective despite the absence of a preexisting C2 auxiliary group. We provide evidence that the directing effect is mediated by the C2 hydroxyl itself via the putative formation of a cis-fused bicyclic intermediate.