6115-03-3Relevant articles and documents
Regio- and chemoselective intermolecular hydroamination of allyl imines for the synthesis of 1,2-diamines
Ickes, Andrew R.,Ensign, Seth C.,Gupta, Anil K.,Hull, Kami L.
supporting information, p. 11256 - 11259 (2014/09/29)
The synthesis of 1,2-diamines via a Rh-catalyzed intermolecular hydroamination of N-allyl imines with cyclic amines is presented. Coordinating groups proximal to the olefin bind to the catalyst and promote the transformation. The reaction affords 1,2-diam
An imine addition/ring-closing metathesis approach to the spirocyclic core of halichlorine and pinnaic acid.
Wright,Schulte II,Page
, p. 1847 - 1850 (2007/10/03)
[reaction: see text] An approach to the spirocyclic core of halichlorine and pinnaic acid has been designed around an imine allylation/ring-closing metathesis sequence. This sequence has been used to generate several azabicylo[n.5] model systems. A newly
Regioselective Aza-Cope Rearrangement of α-Halogenated and Nonhalogenated Imines
Welch, John T.,Corte, Bart De,Kimpe, Norbert De
, p. 4981 - 4983 (2007/10/02)
The 3-aza-Cope rearrangement of α-halogenated and nonhalogenated ketimines by deprotonation of the corresponding iminium salts was found to be an especially facile and regioselective process.Deuterium labeling studies supported the proposed mechanism which required the rearrangement to be highly concerted.
