61167-63-3Relevant academic research and scientific papers
Enantiospecific total synthesis of phytoalexins, (+)-solanascone, (+)-dehydrosolanascone, and (+)-anhydro-β-rotunol
Srikrishna,Ramasastry
, p. 7373 - 7376 (2007/10/03)
Enantiospecific total synthesis of the phytoalexins, solavetivone, anhydro-β-rotunol, solanascone, and dehydrosolanascone, starting from the readily available monoterpene, (R)-carvone has been accomplished.
Total synthesis of (-)-solavetivone using enantioselective copper-catalysed conjugate addition of Me3Al to a cyclohexa-2,5-dienone intermediate
Takemoto, Yoshiji,Kuraoka, Satoru,Ohra, Taiichi,Yonetoku, Yasuhiro,Iwata, Chuzo
, p. 1655 - 1656 (2007/10/03)
By applying a new enantioselective Cu-catalysed conjugate addition of Me3Al, (-)-solavetivone 1 is synthesized stereoselectively from cyclohexa-2,5-dienone 4, prepared from a chiral compound 6 using a regioselective HgII-mediated cyc
