61203-97-2Relevant academic research and scientific papers
Aliphatic Liquid Crystals, 9. - Stereospecific Reduction of 1-Acyl- to 1-Alkyl-4-phenylcyclohexanes
Sucrow, Wolfgang,Heider, RRoland,Joraschek, Norbert
, p. 1039 - 1044 (2007/10/02)
The title reaction - important for the synthesis of aliphatic liquid crystals - is accomplished by reduction of the tosylhydrazones with sodium cyanoborohydride.While the trans-configurated model ketones 6a, 7a give the tosylhydrazones 10a, 11a, and these
CONVENIENT SYNTHESIS OF 4-(TRANS-4 prime -N-ALKYLCYCLOHEXYL) BENZOIC ACIDS.
Szczucinski,Dabrowski
, p. 55 - 64 (2007/10/02)
A convenient method of obtaining 4-(trans-4 prime -n-alkylcyclohexyl) benzoic acids from alkanoyl chlorides, cyclohexane and benzene is described. Homologous series of above mentioned acids and their nitriles with alkyl tail 2 to 10 carbon atoms were prepared and temperatures of their phase transitions were determined.
