612090-74-1Relevant articles and documents
Synthesis of the C(18)-C(34) fragment of amphidinolide C and the C(18)-C(29) fragment of amphidinolide F
Roy, Sudeshna,Spilling, Christopher D.
supporting information; experimental part, p. 5326 - 5329 (2011/01/05)
A convergent synthesis of the C(18)-C(34) fragment of amphidinolide C and the C(18)-C(29) fragment of amphidinolide F is reported. The approach involves the synthesis of the common intermediate tetrahydrofuranyl-β- ketophosphonate via cross metathesis, Pd
Diastereoselective Palladium-Catalyzed Formate Reduction of Allylic Carbonates as a New Entry into Propionate Units
Lautens, Mark,Paquin, Jean-Francois
, p. 3391 - 3394 (2007/10/03)
(Equation presented) The diastereoselective palladium-catalyzed formate reduction of allylic carbonates is described. Reduction of allylic carbonates under mild conditions (Pd(OAc)2 (2.5-5 mol %), [n-Bu 3PH]BF4 (2.5-5 mol