207120-79-4

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 556-82-1 3-methyl-2-buten-1-ol 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 167687-19-6 (2E)-4-[(4-methoxyphenyl)methoxy]-2-methylbut-2-en-1-ol 
• 870474-22-9 3-{[(4-methoxyphenyl)methoxy]methyl}-2,2-dimethyloxirane 
• 688762-39-2 (E)-6-(4-methoxy-benzyloxy)-4-methyl-hex-4-en-1-ol 
• 688762-43-8 1-((E)-6-iodo-3-methyl-hex-2-enyloxymethyl)-4-methoxy-benzene 
• 688762-37-0 (E)-6-(4-methoxy-benzyloxy)-4-methyl-hex-4-enoic acid ethyl ester 
• 688762-47-2 (E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol 
• 688762-74-5 (E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol 
• 688762-49-4 (E)-8-(4-methoxybenzyloxy)-2,6-dimethyl-oct-6-en-1-ol 
• 688762-41-6 (E)-8-(4-methoxy-benzyloxy)-2,6-dimethyl-oct-6-enoic acid ethyl ester 
• 688762-53-0 acetic acid (E)-(S)-8-(4-methoxy-benzyloxy)-2,6-dimethyl-oct-6-enyl ester 
• 688762-45-0 2-[(E)-6-(4-methoxy-benzyloxy)-4-methyl-hex-4-enyl]-2-methyl-malonic acid diethyl ester 
• 688762-95-0 3,5-dioxo-hexanoic acid (E)-(S)-8-(4-methoxy-benzyloxy)-2,6-dimethyl-oct-6-enyl ester 
• 1180481-32-6 C₂₁H₃₆O₂Si 
• 197227-70-6 (2E)-4-[(4-methoxybenzyl)oxy]-2-methylbut-2-enal 

Relevant academic research and scientific papers

Synthesis of the C(18)-C(34) fragment of amphidinolide C and the C(18)-C(29) fragment of amphidinolide F

A convergent synthesis of the C(18)-C(34) fragment of amphidinolide C and the C(18)-C(29) fragment of amphidinolide F is reported. The approach involves the synthesis of the common intermediate tetrahydrofuranyl-β- ketophosphonate via cross metathesis, Pd

Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds

Allylic ethers undergo insertions of silylenes into C-O bonds to form allylic silanes. Silylene insertion into C-O acetal bonds was also observed. Formation of silylene ylide intermediates led to [1,2]-Stevens rearrangement products as well as [2,3]-sigma

Total synthesis of milbemycins: A synthesis of (6R)-6-hydroxy-3,4- dihydromilbemycin E

Following studies using benzyloxymethyl isopropenyl ketone 5 and ethyl 3-(3-furyl)-3-oxopropanoate 6, Robinson reactions between aryloxymethyl isopropenyl ketones 19 and 5 and ethyl 3-(2-trimethylsilyl-3-furyl)-3- oxopropanoate 20 were found to be stereos

Asymmetric synthesis of (E)- and (Z)-3,7-dimethyl-2-octene-1,8-diol and callosobruchusic acid

Both enantiomers and regioisomers of (E)- and (Z)-3,7-dimethyl-2-octene-1, 8-diol and callosobruchusic acid, which have important biological activity were synthesized by enzymatic transesterification of primary alcohols (E)- and (Z)-10.

Study of the stability of carbocations by chlorosulfonyl isocyanate reaction with ethers

The stability order of various alkyl, allyl, and benzyl carbocations was investigated using the novel technique for comparing the stability of carbocations in solution developed by using a simple CSI reaction with various ethers. The p-methoxycinnamyl carbocation was the most stable in our reaction system and the next stable carbocation was the p-methoxybenzyl carbocation. The stability of the other carbocations decreased with methacryl, t-butyl, cinnamyl, acryl, benzyl, 2° and allyl carbocations in that order.

Zeolite β-Induced Rearrangement of Alkoxybenzyl Allyl Ethers to Aldehydes and Ketones. 5.1 Variation of the Allylic Moiety

Allylic PMB ethers rearranged in the presence of zeolite β to form 4-arylbutanals or 5-arylpentanones depending on the substituent pattern of the allylic moiety. Best results were obtained with substrates carrying simple substituents in the allylic 2-posi