61248-51-9

Basic information

• Product Name: cis-2H-1,3,3a,4,5,6,7,7a-octahydro-7a-methyl-2-indenone
• CAS NO: 61248-51-9
• Molecular Weight: 152.236
• Mol File: 61248-51-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: cis-2H-1,3,3a,4,5,6,7,7a-octahydro-7a-methyl-2-indenone(CAS DataBase Reference)
• NIST Chemistry Reference: cis-2H-1,3,3a,4,5,6,7,7a-octahydro-7a-methyl-2-indenone(61248-51-9)
• EPA Substance Registry System: cis-2H-1,3,3a,4,5,6,7,7a-octahydro-7a-methyl-2-indenone(61248-51-9)

Safety Data

• Hazardous Substances Data: 61248-51-9(Hazardous Substances Data)

Upstream product

• 130082-70-1 (2E/Z,3aα,7aβ)-Octahydro-3a-methyl-2-(phenylmethylene)-1H-indene 
• 43206-33-3 1β-methylcyclohexane-1α,2β-diacetic acid 
• 43206-33-3 (+/-)-(1-methyl-cyclohexane-1r,2c-diyl)-di-acetic acid 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 938-06-7 (+-)-4a-methyl-cis-octahydro-naphthalen-2-one 
• 6126-53-0 2-(2-oxopropyl)cyclohexanone 
• 39163-29-6 1,4,5,6,7,7a-hexahydro-inden-2-one 
• 15681-48-8 lithium dimethylcuprate 
• 157944-25-7 1-diazo-3-(1-methylcyclohexyl)propan-2-one 
• 74676-00-9 Trimethyl-[1-(2-methylene-cyclohexylmethyl)-vinyloxy]-silane 
• 938-07-8 trans-10-methyldecal-2-one 
• 6939-71-5 hexahydro-isobenzo[c]furan-1-one 
• 130082-72-3 (2E/Z,3aα,7aβ)-methyl 2,4,6-tris(1-methylethyl)benzenesulfonate 
• 130082-85-8 Methyl cis-1-(3-phenyl-2-propynyl)-2-<(phenylseleno)methyl>cyclohexanecarboxylate 

Downstream Products

• 22920-01-0 cis-2-methyl-2-carboxy-cyclohexane-1-acetic acid 
• 54725-16-5 Δ³⁽¹⁾-8-Methyl-hydrindenon-(2) 
• 22920-01-0 ((1S)-2t-carboxy-2c-methyl-cyclohex-r-yl)-acetic acid 

Relevant articles and documents

Construction of trans-Ring-fused Compounds by Radical Cyclization

Enolates derived from bicyclic lactones of type (4) are alkylated with prop-2-ynylic (and allylic) bromides to give products (5) in which the unsaturated alkyl group is syn to the remaining ring-fusion hydrogen; prop-2-ynylic aldehydes can be used instead

A synthetic approach to perhydro-3-isoquinolinones bearing an angular methyl group via organocuprate addition

The addition of organocuprates to the activated C-C double bond in 2H-3,3a,4,5,6,7-hexahydro-2-indenone followed by trapping of the anionic intermediate with Mel as electrophile is reported. Structural assignment of the resulting product was carried out v

Formation of trans Ring-Fused Compounds by an Alkylation-Radical Cyclization Sequence

Enolates derived from bicyclic lactones of type 1 (Scheme I) can be alkylated with 2-propynylic halides to give products 2, in which the unsaturated alkyl group is syn to the adjacent ring-fusion hydrogen.Reaction of 2 with sodium phenyl selenide and then