61260-16-0Relevant academic research and scientific papers
A facile and practical preparation ofP-chiral phosphine oxides
Xu, Ronghua,Gao, Zhenhua,Yu, Yiteng,Tang, Yehua,Tian, Duanshuai,Chen, Tian,Chen, Yibing,Xu, Guangqing,Shi, Enxue,Tang, Wenjun
, p. 3335 - 3338 (2021/04/07)
A practical and cost-effective synthetic method ofP-chiral diarylalkyl, aryldialkyl, and triaryl phosphine oxides by using readily available chiral diphenyl-2-pyrrolidinemethanol as the auxiliary is developed. The long-standing racemization issue during s
Phosphine boranes as less hydrophobic building blocks than alkanes and silanes: Structure-property relationship and estrogen-receptor-modulating potency of 4-phosphinophenol derivatives
Fujii, Shinya,Hashimoto, Yuichi,Matsumoto, Yuichiro,Saito, Hiroki
, (2020/01/28)
Increasing structural options in medicinal chemistry is important for the development of novel and distinctive drug candidates. In this study, we focused on phosphorus-containing functionalities. We designed and synthesized a series of phosphinophenol der
Lewis acid catalyzed room-temperature Michaelis-Arbuzov rearrangement
Renard, Pierre-Yves,Vayron, Philippe,Leclerc, Eric,Valleix, Alain,Mioskowski, Charles
, p. 2389 - 2392 (2007/10/03)
The taming of the shrew! For the first time, a broadly applicable efficient room-temperature Arbuzov rearrangement is described. This reaction is accomplished through an atom-economical Lewis acid catalyzed process (see scheme, TMSOTf=trimethylsilyl trifluoromethane-sulfonate). The method has been generalized to primary and activated secondary phosphites, phosphinites, and phosphonites.
Organoelement juvenile hormone mimetics
Kolodiazhnyi, Oleg I.,Sheiko, Sergei,Liashenko, Daria,Baranova, Ludmila,Roditakis, Nikos
, p. 171 - 183 (2007/10/03)
The synthesis of new organophosphorus and organosilicon compounds possessing insect juvenile hormone activity is described. The structure of the prepared compounds is confirmed by NMR spectra.
SYNTHESIS OF THE TERTIARY PHOSPHINE OXIDES POSSESSING JUVENILE HORMONE ACTIVITY
Kolodiazhnyi, O. I.,Zemlianoy, V. N.,Baranova, L. I.,Shurubura, G. V.
, p. 137 - 140 (2007/10/02)
The synthesis of the first organophosphorus compounds (1a-d) possessing insect juvenile hormone activity is described.The structure of the compounds (1a-d) is confirmed by IR and NMR spectra.Key words: Tertiary phosphine oxides; phenols phosphorylated; ph
