612841-87-9

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 753502-53-3 (2R,3S,4S,5R,6R)-4-Benzyloxy-2-hydroxymethyl-6-isopropoxy-2-vinyl-tetrahydro-pyran-3,5-diol 
• 612841-73-3 1,2,4,6-tetra-O-acetyl-3-O-benzyl-5-C-vinyl-β-D-glucopyranoside 
• 612841-85-7 isopropyl 2,4,6-tri-O-acetyl-3-O-benzyl-5-C-vinyl-β-D-glucopyranoside 

Downstream Products

• 918302-30-4 8-benzyloxy-6-isopropoxy-2-phenyl-4a-vinyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-7-one 
• 918302-23-5 4,5-bis-benzyloxy-6-hydroxymethyl-2-isopropoxy-3,6-divinyl-tetrahydro-pyran-3-ol 
• 918302-22-4 8-benzyloxy-6-isopropoxy-2-phenyl-4a,7-divinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 918302-27-9 7-allyl-8-benzyloxy-6-isopropoxy-2-phenyl-4a-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 612841-89-1 isopropyl 3-O-benzyl-4,6-O-benzylidene-2-O,5-C-methylene-β-D-glucopyranoside 
• 612841-88-0 isopropyl 3-O-benzyl-4,6-O-benzylidene-5-C-hydroxymethyl-β-D-glucopyranoside 
• 753502-52-2 Toluene-4-sulfonic acid (2R,4aS,6R,7R,8R,8aS)-8-benzyloxy-7-hydroxy-6-isopropoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-4a-ylmethyl ester 

Relevant academic research and scientific papers

RCM as a tool to freeze conformation of monosaccharides: synthesis of a β-mannopyranoside mimic adopting a conformation close to the biologically relevant B2,5 boat

The synthesis of a β-d-mannopyranoside analog, fully identical to the naturally occurring d-mannopyranose in terms of hydroxyl pattern, and displaying a skew-boat conformation close to a B2,5 boat strongly believed to be adopted by the oxycarbe

Synthesis and acid catalyzed hydrolysis of B2,5 type conformationally constrained glucopyranosides: Incorporation into a cellobiose analogue

Isopropyl and p-nitrophenyl α- and β-D-glucopyranosides, restrained in a conformation close to B2,5 via an oxymethylene bridge have been synthesized. These four glucopyranosides were found to be hydrolyzed at similar rates, close to those obser

Synthesis of B2,5 type conformationally constrained glucopyranosides

Isopropyl and p-nitrophenyl α- and β-D-glucopyranosides restrained in a conformation close to B2,5 have been synthesized. They are all hydrolyzed at similar rates, close to those observed for the parent unlocked glucosides.