753502-53-3

Upstream product

• 612841-85-7 isopropyl 2,4,6-tri-O-acetyl-3-O-benzyl-5-C-vinyl-β-D-glucopyranoside 
• 612841-73-3 1,2,4,6-tetra-O-acetyl-3-O-benzyl-5-C-vinyl-β-D-glucopyranoside 

Downstream Products

• 612841-87-9 isopropyl 3-O-benzyl-4,6-O-benzylidene-5-C-vinyl-β-D-glucopyranoside 
• 612841-89-1 isopropyl 3-O-benzyl-4,6-O-benzylidene-2-O,5-C-methylene-β-D-glucopyranoside 
• 612841-88-0 isopropyl 3-O-benzyl-4,6-O-benzylidene-5-C-hydroxymethyl-β-D-glucopyranoside 
• 753502-52-2 Toluene-4-sulfonic acid (2R,4aS,6R,7R,8R,8aS)-8-benzyloxy-7-hydroxy-6-isopropoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-4a-ylmethyl ester 
• 918302-27-9 7-allyl-8-benzyloxy-6-isopropoxy-2-phenyl-4a-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 918302-22-4 8-benzyloxy-6-isopropoxy-2-phenyl-4a,7-divinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 918302-23-5 4,5-bis-benzyloxy-6-hydroxymethyl-2-isopropoxy-3,6-divinyl-tetrahydro-pyran-3-ol 
• 918302-30-4 8-benzyloxy-6-isopropoxy-2-phenyl-4a-vinyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-7-one 
• 753502-54-4 (4aR,6R,7R,8R,8aS)-8-Benzyloxy-6-isopropoxy-2,2-dimethyl-4a-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 

Relevant academic research and scientific papers

Synthesis of B2,5 type conformationally constrained glucopyranosides

Isopropyl and p-nitrophenyl α- and β-D-glucopyranosides restrained in a conformation close to B2,5 have been synthesized. They are all hydrolyzed at similar rates, close to those observed for the parent unlocked glucosides.

RCM as a tool to freeze conformation of monosaccharides: synthesis of a β-mannopyranoside mimic adopting a conformation close to the biologically relevant B2,5 boat

The synthesis of a β-d-mannopyranoside analog, fully identical to the naturally occurring d-mannopyranose in terms of hydroxyl pattern, and displaying a skew-boat conformation close to a B2,5 boat strongly believed to be adopted by the oxycarbe

Synthesis and acid catalyzed hydrolysis of B2,5 type conformationally constrained glucopyranosides: Incorporation into a cellobiose analogue

Isopropyl and p-nitrophenyl α- and β-D-glucopyranosides, restrained in a conformation close to B2,5 via an oxymethylene bridge have been synthesized. These four glucopyranosides were found to be hydrolyzed at similar rates, close to those obser