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61295-92-9

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61295-92-9 Usage

Uses

Methyl 2-Cyano-2-oximinoacetate is an intermediate in synthesizing 2-Cyano-2-(methoxyimino)acetic Acid (C989423), which is a cyano-oxime derivative used as a fungicide.

Check Digit Verification of cas no

The CAS Registry Mumber 61295-92-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,1,2,9 and 5 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 61295-92:
(7*6)+(6*1)+(5*2)+(4*9)+(3*5)+(2*9)+(1*2)=129
129 % 10 = 9
So 61295-92-9 is a valid CAS Registry Number.
InChI:InChI=1/C4H4N2O3/c1-9-4(7)3(2-5)6-8/h8H,1H3

61295-92-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name methyl (2E)-2-cyano-2-hydroxyiminoacetate

1.2 Other means of identification

Product number -
Other names 2-cyano-2-oximino acetic acid methyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:61295-92-9 SDS

61295-92-9Relevant articles and documents

An efficient strontium-based combustion inhibitor of ammonium perchlorate with a 2D-MOF structure

Huang, Yao,Peng, Rufang,Jin, Bo

, p. 11068 - 11074 (2021/07/06)

In this study, a new strontium 2D-MOF, {[Sr(AFCA)2(H2O)2]·2H2O}n(AFCA = 4-aminofurazan-3-carboxylic acid), was successfully prepared by slow evaporation at room temperature. Its structure was characterized by X-ray single-crystal diffractometry. DTA as an efficient thermal analysis method was used in this study to have a better understanding of the thermal decomposition of ammonium perchlorate (AP). The Kissinger and the Ozawa-Doyle methods were also applied to determine the apparent activation energy (E) and the pre-exponential factor (A) of AP thermal decomposition. After the addition of {[Sr(AFCA)2(H2O)2]·2H2O}nin AP, there is an increase of 85.97 °C in the LTD stage of AP thermal decomposition and an insignificant decrease of 24.32 °C in the HTD stage. With the help of the TG-DSC-DTG method, we analyse the catalytic mechanism of AP in the LTD stage in detail. {[Sr(AFCA)2(H2O)2]·2H2O}ncan act as an efficient combustion inhibitor for AP thermal decomposition.

New Route to Polynuclear Ni(II) and Cu(II) Complexes with Bridging Oxime Groups That Are Inaccessible by Conventional Preparations

Opalade, Adedamola A.,Gomez-Garcia, Carlos J.,Gerasimchuk, Nikolay

, p. 678 - 693 (2019/02/14)

A series of new polynuclear complexes of divalent Ni and Cu with 2-cyano-2-oximino-acetic acid (later AACO2-) were obtained as the result of the ligand modification reaction in the process of complexation, using 2-cyano-2-oximino-acetates such as methyl- (later as MeCO), and ethyl- (as ECO later on). Synthesized compounds were characterized by spectroscopic methods, thermal analysis, magnetochemistry, and X-ray crystallography. Crystal data revealed the formation of the dimeric [Ni(AACO)(H2O)3]2·H2O (1), trimeric K2[Ni3(AACO)4(H2O)4]·4H2O (2), and K2[Cu3(AACO)4(H2O)4]·4H2O (3) complexes, with bridging NO-groups cyanoxime dianions. In the latter two compounds, the AACO2- anions adopt cis-arrangements around metal centers. One mononuclear complex of K2[Cu(AACO)2(H2O)]·2H2O (4) composition was isolated and characterized as well, where the cyanoxime forms the trans-complex 4. There is moderate-to-strong antiferromagnetic coupling between metal centers in polynuclear complexes. Data of thermal analysis studies revealed high-energy properties for dehydrated complexes 3 and 4, which violently decompose at ~200 °C. These compounds may be viewed as room temperature completely safe, but heat-triggered actuators, because of their pronounced mechanical action upon leaving the system (crucible). Final products of thermal decomposition are Ni and NiO for 1, and the mixture of NiO and K2O for 2, with metallic copper for 3 and 4.

Crystal structures of the "two" 4-aminofurazan-3-carboxylic acids

Willer, Rodney L.,Storey, Robson F.,Frisch, Mark,Deschamps, Jeffery R.

experimental part, p. 227 - 231 (2012/05/05)

The crystal structures of the two compounds reported to be 4-aminofurazan-3-carboxylic acid have been determined. The compound reported by Sheremetev et al. (J Heterocycl Chem 2005, 42, 519) is the actual 4-aminofurazan-3-carboxylic acid. The compound reported by Meyer (Org Prep Proced Int 2004, 36, 361) is the interesting complex formed from a molecule of the acid and a molecule of the potassium salt of the acid..

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