6135-40-6Relevant articles and documents
Catalytic metathesis of carbon dioxide with heterocumulenes mediated by titanium isopropoxide
Ghosh, Rajshekhar,Samuelson, Ashoka G.
, p. 2017 - 2019 (2007/10/03)
The insertion of an isopropoxide ligand of titanium isopropoxide into heterocumulenes gives a product that carries out metathesis at elevated temperatures by undergoing insertion of a second heterocumulene in a head to head fashion, followed by an extrusion reaction. The Royal Society of Chemistry 2005.
Reaction of isocyanates with alkyl N-phenylcarbamates
Gorbatov,Yablokova,Kheidorov
, p. 610 - 612 (2007/10/03)
Alkyl N-phenylcarbamates accelerate thermolysis of isocyanates by forming with the latter at the first stage of the thermolysis a donor-acceptor complex. The accelerative effect of the carbamates is enhanced by increasing electron-donor power of substituents in the carbamates and increasing electron-donor power of the isocyanates.