61357-37-7Relevant academic research and scientific papers
On the reactivity of C(sp3)-H σ-bonds: Oxygenation with methyl(trifluoromethyl)dioxirane
Mello, Rossella,Royo, Jorge,Andreu, Cecilia,Baguena-Ano, Minerva,Asensio, Gregorio,Gonzalez-Nunez, Maria Elena
, p. 455 - 466 (2008)
The reactivity of C-H σ-bonds of a series of 2-substituted adamantanes 2 towards methyl(trifluoromethyl)dioxirane (1) shows a consistent dependence on the electron-withdrawing ability, either inductive or by resonance, of the substituent. The results are
CHARGE DISPERSAL IN 1- AND 2-ADAMANTYL CATIONS
Grob, Cyril A.,Wang, Guangyi,Yang, Chengxi
, p. 1247 - 1250 (2007/10/02)
Substituents at the remoter 5-position of 2-adamantyl arylsulfonates controlsolvolysis rates more strongly than substituents the 4-position.
