61375-52-8Relevant articles and documents
Synthesis of (dl)-trichodiene using novel ring transformation reaction
Tanaka,Sakai
, p. 5581 - 5584 (2007/10/02)
Synthesis of (dl)-trichodiene has been completed via novel ring transformation reaction using TsOH/ethylene glycol.
Stereoselective Synthesis of (+/-)-Trichodiene
Snowden, Roger L.,Sonnay, Philippe
, p. 1464 - 1465 (2007/10/02)
A stereoselective synthesis of (+/-)-trichodiene (1) is described whose key step is the conversion of the tricyclic, homoallylic alcohol 3, via β-fragmentation of its potassium alkoxide 3a, to cyclopentanone 2.
Stereoselective Total Synthesis of (+/-)-Trichodiene: Biogenetic Precursor of the Trichothecane Sesquiterpenoids
Welch, Steven C.,Rao, A.S.C. Prakasa,Gibbs, Charles G.,Wong, Rayman Y.
, p. 4077 - 4085 (2007/10/02)
Two approaches to the total synthesis of (+/-)-trichodiene (1) are reported from cis-fused lactone 10.Sequential alkylation of lactone 10 was observed to be highly stereoselective as established by the construction of diastereomeric lactone esters 12 and