74592-37-3

Upstream product

• 37720-05-1 (1,4-Dimethyl-2-oxo-cyclohexyl)-acetic acid 
• 74592-60-2 (1,4-Dimethyl-2-oxo-cyclohexyl)-acetaldehyde 
• 37720-04-0 2,5-Dimethyl-2-(3-propenyl)cyclohexanone 
• 932-51-4 2,5-dimethylcyclohexanone 
• 37720-06-2 Ethyl 1,4-Dimethyl-2-oxo-1-cyclohexaneacetate 

Downstream Products

• 74592-59-9 (2SR,1'SR)-2-(1',4'-dimethylcyclohex-3'-enyl)-2-methylcyclopentan-1-one 
• 62096-97-3 Methyl((1α,2α)-2-Hydroxy-1,4-dimethyl-3-cyclohexen-1-yl)-3-methyl-2-oxocyclopentanecarboxylate 
• 74644-00-1 Methyl 3-(1,4-Dimethyl-2-cyclohexen-1-yl)-3β-2-oxocyclopentanecarboxylate 
• 62096-98-4 Methyl 3-Methyl-3-(1-methyl-4-methylene-2-cyclohexenyl)-2-oxocyclopentanecarboxylate 
• 74643-99-5 Methyl 3-(1,4-Dimethyl-3-cyclohexen-1-yl)-3β-methyl-2-oxocyclopentanecarboxylate 
• 62096-99-5 2-Methyl-2-(1-methyl-4-methylene-2-cyclohexen-1-yl)-cyclopentanone 
• 61431-50-3 (2RS,1'SR,4'SR)-2-(1',4'-dimethylcyclohex-2'-enyl)-2-methylcyclopentan-1-one 
• 62097-00-1 2-Methyl-2-(1-methyl-4-methylene-2-cyclohexen-1-yl)-cyclopentanol 
• 62097-01-2 2-Methyl-2-(1-methyl-4-methylenecyclohex-1-yl)cyclopentanone 
• 37720-03-9 1,4-Dimethyl-2-oxo-3-cyclohexeneacetic acid 
• 61375-52-8 (2RS,1'SR)-2-(1',4'-dimethylcyclohex-3'-enyl)-2-methylcyclopentan-1-one 
• 61505-17-7 (+/-)-trichodiene 
• 37720-07-3 ethyl (1,4-dimethyl-2-oxocyclohex-3-enyl)acetate 

Relevant academic research and scientific papers

Stereoselective Total Synthesis of (+/-)-Trichodiene: Biogenetic Precursor of the Trichothecane Sesquiterpenoids

Two approaches to the total synthesis of (+/-)-trichodiene (1) are reported from cis-fused lactone 10.Sequential alkylation of lactone 10 was observed to be highly stereoselective as established by the construction of diastereomeric lactone esters 12 and